Redox-induced reactions of nickel maleonitriledithiolate αα′-di-imine complexes

Bowmaker, Graham; Boyd, Peter; Campbell, GK

dc.contributor.author	Bowmaker, Graham	en
dc.contributor.author	Boyd, Peter	en
dc.contributor.author	Campbell, GK	en
dc.date.accessioned	2011-12-20T20:17:06Z	en
dc.date.issued	1983	en
dc.identifier.citation	Journal of the Chemical Society, Dalton Transactions 1019-1021 1983	en
dc.identifier.issn	1472-7773	en
dc.identifier.uri	http://hdl.handle.net/2292/10250	en
dc.description.abstract	The complex [NiII{(NC)2C2S2}{(CH3)2C2N2Ph2}] has been found to undergo one-electron reduction to a species containing NiI. This species is unstable and disproportionates to the known [NiII{(NC)2C2S2}2]2– and [Ni{(CH3)2C2N2Ph2}2]. The complex also reacts upon oxidation to give [Ni{(NC)2C2S2}2]–. A similar one-electron reduction of [Ni(Ph2C2S2)(phen)](phen =1,10-phenanthroline) has been found to give a stable species with greater delocalisation of the unpaired electron over the ligand.	en
dc.publisher	Royal Society of Chemistry	en
dc.relation.ispartofseries	Journal of the Chemical Society, Dalton Transactions	en
dc.rights	Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher.	en
dc.rights.uri	https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm	en
dc.title	Redox-induced reactions of nickel maleonitriledithiolate αα′-di-imine complexes	en
dc.type	Journal Article	en
dc.identifier.doi	10.1039/DT9830001019	en
pubs.issue	5	en
pubs.begin-page	1019	en
dc.rights.holder	Copyright: Royal Society of Chemistry	en
pubs.end-page	1021	en
pubs.publication-status	Published	en
dc.rights.accessrights	http://purl.org/eprint/accessRights/RestrictedAccess	en
pubs.subtype	Article	en
pubs.elements-id	141900	en
pubs.record-created-at-source-date	2010-09-29	en