A concise synthesis of (±) and a total synthesis of (+)-epiquinamide

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dc.contributor.author Tong, Sok en
dc.contributor.author Barker, David en
dc.date.accessioned 2012-02-27T20:02:30Z en
dc.date.issued 2006 en
dc.identifier.citation Tetrahedron Letters 47(29):5017-5020 17 Jul 2006 en
dc.identifier.issn 0040-4039 en
dc.identifier.uri http://hdl.handle.net/2292/12137 en
dc.description.abstract A total synthesis of the quinolizidine alkaloid (+)-epiquinamide 1 has been achieved starting from ()-pipecolinic acid 3. The key step is the highly diastereoselective addition of a TBDMS-protected propargyl alcohol to a chiral aldehyde derived from 3 to give erythro alkynol 19, which is then easily transformed into the desired bicyclic skeleton. en
dc.description.uri http://dx.doi.org/10.1016/j.tetlet.2006.05.092 en
dc.publisher Elsevier Ltd. en
dc.relation.ispartofseries Tetrahedron Letters en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0040-4039/ en
dc.rights.uri https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm en
dc.title A concise synthesis of (±) and a total synthesis of (+)-epiquinamide en
dc.type Journal Article en
dc.identifier.doi 10.1016/j.tetlet.2006.05.092 en
pubs.issue 29 en
pubs.begin-page 5017 en
pubs.volume 47 en
dc.rights.holder Copyright: Elsevier Ltd. en
pubs.end-page 5020 en
dc.rights.accessrights http://purl.org/eprint/accessRights/RestrictedAccess en
pubs.subtype Article en
pubs.elements-id 65814 en
pubs.org-id Science en
pubs.org-id Chemistry en
pubs.record-created-at-source-date 2010-09-01 en

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