dc.contributor.author |
Zhu, K |
en |
dc.contributor.author |
Iacono, ST |
en |
dc.contributor.author |
Budy, SM |
en |
dc.contributor.author |
Jin, Jianyong |
en |
dc.contributor.author |
Smith, DW |
en |
dc.date.accessioned |
2012-02-28T19:06:19Z |
en |
dc.date.issued |
2010-05-01 |
en |
dc.identifier.citation |
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 48(9):1887-1893 01 May 2010 |
en |
dc.identifier.issn |
0887-624X |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/12226 |
en |
dc.description.abstract |
A diverse pool of aryl bistrifluorovinyl ether (BTFVE) compounds with reactive pendant groups were prepared in a facile, high yielding three step "one-pot" synthesis from commercial 4-bromo(trifluorovinyloxy)benzene. Monomers were confirmed from ATR-FTIR, (1)H, (13)C, and (19)F NMR, and HRMS analysis. Aryl BTFVE compounds were thermally polymerized to afford perfluorocyclobutyl (PFCB) aryl ether polymers with high number average molecular weight (M(n)) for homopolymers (17,050-27,090) and copolymers with 4,4'-bis(trifluorovinyloxy)biphenyl monomers (27,860-56,500). The PFCB aryl ether homo- and copolymers collectively possess high thermal stability (>299 degrees C in N(2)) and are readily solution processable producing optically transparent films. The thermal polymerization was achieved and reactive moieties remained intact, aside from those functionalized with acrylates. In the case with acrylate functionalized polymers, orthogonal polymerization was achieved by first photopolymerizing the acrylates followed by thermal curing of the aryl trifluorovinyl ether endgroups. Preliminary results in this study produced the successful preparation of photodefinable PFCB aryl ether material. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1887-1893, 2010 |
en |
dc.language |
English |
en |
dc.publisher |
Wiley Periodicals, Inc. |
en |
dc.relation.ispartofseries |
Journal of Polymer Science Part A: Polymer Chemistry |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0887-624X/ |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.subject |
Science & Technology |
en |
dc.subject |
Physical Sciences |
en |
dc.subject |
Polymer Science |
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dc.subject |
aryl trifluorovinyl ethers |
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dc.subject |
fluoropolymers |
en |
dc.subject |
lithography |
en |
dc.subject |
PFCB aryl ether polymers |
en |
dc.subject |
polyethers |
en |
dc.subject |
ABA TRIBLOCK COPOLYMER |
en |
dc.subject |
PHENYLPHOSPHINE OXIDE |
en |
dc.subject |
HIGHLY EFFICIENT |
en |
dc.subject |
POLYMERS |
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dc.subject |
FLUOROPOLYMERS |
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dc.title |
Facile One-Pot Synthesis and Thermal Cyclopolymerization of Aryl Bistrifluorovinyl Ether Monomers Bearing Reactive Pendant Groups |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1002/pola.23953 |
en |
pubs.issue |
9 |
en |
pubs.begin-page |
1887 |
en |
pubs.volume |
48 |
en |
dc.rights.holder |
Copyright: Wiley Periodicals, Inc. |
en |
pubs.author-url |
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=000277017800005&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=6e41486220adb198d0efde5a3b153e7d |
en |
pubs.end-page |
1893 |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
247472 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
pubs.record-created-at-source-date |
2012-08-10 |
en |