dc.contributor.author |
Somerville, Robyn Faith (nee Ogilvie) |
en |
dc.date.accessioned |
2007-09-03T10:25:12Z |
en |
dc.date.available |
2007-09-03T10:25:12Z |
en |
dc.date.issued |
1987 |
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dc.identifier |
THESIS 88-147 |
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dc.identifier.citation |
Thesis (PhD--Chemistry)--University of Auckland, 1987 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/1682 |
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dc.description |
Full text is available to authenticated members of The University of Auckland only. |
en |
dc.description.abstract |
A convenient, high yielding synthesis of bromolactones from unsaturated carboxylic acids has been achieved employing bromine and thallous carbonate. Several methods of bromolactonisation have been compared for a series of substrates. In general the new method affords a higher yield of the bromolactone.
Various strategies to effect singlet oxygen addition to isoprene have been investigated.
A new route to the stereoisomers of 1,4-diacetoxy-2-methyl-1,3-butadiene has been developed resulting in an improved yield. The Diels-Alder reactions of these isomers and 1,2-diphenylsulfonylethylene were unsuccessful. |
en |
dc.language.iso |
en |
en |
dc.publisher |
ResearchSpace@Auckland |
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dc.relation.ispartof |
PhD Thesis - University of Auckland |
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dc.relation.isreferencedby |
UoA9910908314002091 |
en |
dc.rights |
Restricted Item. Available to authenticated members of The University of Auckland. |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. |
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dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
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dc.title |
Bromolactonisations and syntheses towards cyclitols |
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dc.type |
Thesis |
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thesis.degree.discipline |
Chemistry |
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thesis.degree.grantor |
The University of Auckland |
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thesis.degree.level |
Doctoral |
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thesis.degree.name |
PhD |
en |
dc.rights.holder |
Copyright: The author |
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dc.identifier.wikidata |
Q112848573 |
|