Routes to drimanes from podocarpic acid

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dc.contributor.advisor Professor Con Cambie en
dc.contributor.author Grimsdale, Andrew Clive en
dc.date.accessioned 2007-11-14T03:11:17Z en
dc.date.available 2007-11-14T03:11:17Z en
dc.date.issued 1989 en
dc.identifier.citation Thesis (PhD--Chemistry)--University of Auckland. en
dc.identifier.uri http://hdl.handle.net/2292/2072 en
dc.description.abstract The synthesis and ozonolysis of the 6- and 7-substituted 12-hydroxypodocarpatrienes (26), (86), (90), and (98), as a possible route for the synthesis of drimanes from 12-hydroxypodocarpa-8,11,13-trien-19-oic acid (podocarpic acid) (9) has been investigated. Modification of the aromatic ring of (9) has given 11- and l4-hydroxypodocarpatrienes which were ozonised to give the congeners (31), (34), and (36) of the naturally occurring drimanes confertifolin (6), isodrimenin (7), and winterin (8). The oxidation of a 12,13-dihydroxypodocarpatriene (37) and its dimethyl ether (38) have also been investigated. Routes for the conversion of the enone (45) and oxime (230), derived from the ozonolysis products of methyl podocarpate (10), to drimanes have also been investigated. en
dc.format Scanned from print thesis en
dc.language.iso en en
dc.publisher ResearchSpace@Auckland en
dc.relation.ispartof PhD Thesis - University of Auckland en
dc.relation.isreferencedby UoA114251 en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. en
dc.rights.uri https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm en
dc.title Routes to drimanes from podocarpic acid en
dc.type Thesis en
thesis.degree.discipline Chemistry en
thesis.degree.grantor The University of Auckland en
thesis.degree.level Doctoral en
thesis.degree.name PhD en
dc.subject.marsden Fields of Research::250000 Chemical Sciences en
dc.rights.holder Copyright: The author en
pubs.local.anzsrc 03 - Chemical Sciences en
pubs.org-id Faculty of Science en


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