Synthesis of lithium corrole and its use as a reagent for the preparation of cyclopentadienyl zirconium and titanium corrole complexes

Synthesis of lithium corrole and its use as a reagent for the preparation of cyclopentadienyl zirconium and titanium corrole complexes

Buckley, HL ; Chomitz, WA ; Koszarna, B ; Tasior, M ; Gryko, DT ; Brothers, Penelope ; Arnold, J
Identifier: http://hdl.handle.net/2292/21210
Issue Date: 2012
Reference: Chemical Communications 48(87):10766-10768 01 Jan 2012
Rights (URI): https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm

Abstract:

The lithium corrole complex (Mes (p-OMePh)corrole)Li ·6THF (1·6THF), prepared via deprotonation of the free-base corrole with lithium amide, acts as precursor for the preparation of cyclopentadienyl zirconium(iv) corrole (2) and pentamethylcyclopentadienyl titanium(iv) corrole (3).

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DOI: 10.1039/c2cc35984g
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