dc.contributor.advisor |
Dr. F.J. Llewellyn |
en |
dc.contributor.advisor |
Dr. D. Hall |
en |
dc.contributor.author |
Waters, Joyce Mary Partridge |
en |
dc.date.accessioned |
2007-12-02T23:11:07Z |
en |
dc.date.available |
2007-12-02T23:11:07Z |
en |
dc.date.issued |
1960 |
en |
dc.identifier.citation |
Thesis (PhD)--University of New Zealand, 1960. |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/2160 |
en |
dc.description.abstract |
Pauling (1931) introduced the concept of the hybridisation of (n - 1)d, ns and np orbitals to explain the two classes 'ionic' and 'covalent' into which co-ordination compounds of transition metals appeared to fall. These two classes in general have different numbers of unpaired spins, hence they will be distinguished by their magnetic moments. For a series of ferric salts a moment corresponding to either one or five unpaired spins was found, but not intermediate values. I the 'ionic' case the five d-electrons go into the 3d orbitals with their spins parallel giving a moment corresponding to five unpaired spins. I the octahedral case d2 sp3 hybridisation occurs, leaving three d-orbitals to hours the five d-electrons thus giving rise to a moment corresponding to one unpaired spin. |
en |
dc.format |
Scanned from print thesis |
en |
dc.language.iso |
en |
en |
dc.publisher |
ResearchSpace@Auckland |
en |
dc.relation.ispartof |
PhD Thesis - University of Auckland |
en |
dc.relation.isreferencedby |
UoA215822 |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.title |
A study of some co-ordination compounds formed between nickel diammines and the nitrite ion |
en |
dc.type |
Thesis |
en |
thesis.degree.discipline |
Chemistry |
en |
thesis.degree.grantor |
University of New Zealand - Auckland University College |
en |
thesis.degree.level |
Doctoral |
en |
thesis.degree.name |
PhD |
en |
dc.subject.marsden |
Fields of Research::250000 Chemical Sciences |
en |
dc.rights.holder |
Copyright: The author |
en |
pubs.local.anzsrc |
03 - Chemical Sciences |
en |
pubs.org-id |
Faculty of Science |
en |
dc.identifier.wikidata |
Q111964160 |
|