dc.contributor.author |
Gizdavic Nikolaidis, Marija |
en |
dc.contributor.author |
Bennett, J |
en |
dc.contributor.author |
Zujovic, Z |
en |
dc.contributor.author |
Swift, Simon |
en |
dc.contributor.author |
Bowmaker, Graham |
en |
dc.date.accessioned |
2015-04-17T03:27:31Z |
en |
dc.date.available |
2012-04-18 |
en |
dc.date.issued |
2012-08 |
en |
dc.identifier.citation |
Synthetic Metals, 2012, 162 (13–14), pp. 1114 - 1119 (6) |
en |
dc.identifier.issn |
0379-6779 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/25252 |
en |
dc.description.abstract |
The spectroscopic characterization of acetone extracted aniline oligomers (AEAO) of oxidative polymerization of aniline using potassium iodate (KIO3) as oxidant is performed. The chemical structures of AEAO and parent polyaniline (PANI) are investigated by using FTIR, Raman, EPR and NMR spectroscopies. The results showed that aniline oligomers are with cross-linked structure and confirmed similarity of structure with PANI. Antimicrobial activities of AEAO, acetone extracted functionalized aniline oligomers (AEFAO) and commercial oligomers (CO) are determined against Gram-negative bacteria, Gram-positive bacteria and fungi. The length of the polymer chain is shown to contribute to the antimicrobial efficacy of these materials; long-chain functionalized polyaniline (fPANI) polymers are more effective against Gram-negative bacteria than AEFAO and CO. The potential of AEFAO as novel antimicrobials and correlation of their antimicrobial mechanism with the long-chain fPANI polymers are investigated |
en |
dc.language |
eng |
en |
dc.publisher |
Elsevier |
en |
dc.relation.ispartofseries |
Synthetic Metals |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0379-6779/ |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.subject |
Aniline oligomers |
en |
dc.subject |
FTIR |
en |
dc.subject |
Raman spectroscopy |
en |
dc.subject |
EPR |
en |
dc.subject |
NMR |
en |
dc.subject |
Antimicrobial properties |
en |
dc.title |
Characterization and antimicrobial efficacy of acetone extracted aniline oligomers |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1016/j.synthmet.2012.04.031 |
en |
pubs.issue |
13–14 |
en |
pubs.begin-page |
1114 |
en |
pubs.volume |
162 |
en |
dc.rights.holder |
Copyright:
Elsevier |
en |
pubs.author-url |
http://www.sciencedirect.com/science/article/pii/S0379677912001658 |
en |
pubs.end-page |
1119 |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
JOUR |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
357712 |
en |
pubs.org-id |
Medical and Health Sciences |
en |
pubs.org-id |
Medical Sciences |
en |
pubs.org-id |
Molecular Medicine |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
pubs.record-created-at-source-date |
2014-08-15 |
en |