Structural studies of some copper(II) coordination compounds
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Thesis (PhD--Chemistry)--University of Auckland, 1967.
Degree Grantor
The University of Auckland
Abstract
The crystal structures of four coordination compounds of copper(II) have been investigated by three-dimensional X-ray methods. The structure of one crystalline form of bis-(N-ethyl-salicylaldiminato) copper(II) has revealed that the copper atom in such a compound may adopt a tetrahedrally-distorted coordination geometry under less severe steric conditions than had previously been supposed. The structures of a methylamine perchlorate adduct of NN’-ethylenebis-(acetylacetoneiminato) copper(II) and p-nitrophenol and chloroform adducts of NN’-ethylenebis-(salicylaldiminato) copper(II) have indicated that the bonding requirements of the copper atom can be modified by hydrogen bonding involving a ligand atom.
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ANZSRC 2020 Field of Research Codes
03 - Chemical Sciences
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