dc.contributor.author |
Robertson, APM |
en |
dc.contributor.author |
Leitao, Erin |
en |
dc.contributor.author |
Manners, I |
en |
dc.date.accessioned |
2016-10-16T20:54:09Z |
en |
dc.date.issued |
2011-12-07 |
en |
dc.identifier.citation |
Journal of the American Chemical Society, 2011, 133 (48), 19322 - 19325 |
en |
dc.identifier.issn |
0002-7863 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/30748 |
en |
dc.description.abstract |
Ir-catalyzed (20 °C) or thermal (70 °C) dehydrocoupling of the linear diborazane MeNH(2)-BH(2)-NHMe-BH(3) led to the formation of poly- or oligoaminoboranes [MeNH-BH(2)](x) (x = 3 to >1000) via an initial redistribution process that forms MeNH(2)·BH(3) and also transient MeNH═BH(2), which exists in the predominantly metal-bound and free forms, respectively. Studies of analogous chemistry led to the discovery of metal-free hydrogenation of the B═N bond in the "model" aminoborane iPr(2)N═BH(2) to give iPr(2)NH·BH(3) upon treatment with the diborazane Me(3)N-BH(2)-NHMe-BH(3) or amine-boranes RR'NH·BH(3) (R, R' = H or Me). |
en |
dc.description.uri |
https://www.ncbi.nlm.nih.gov/pubmed/22035112 |
en |
dc.format.medium |
Print-Electronic |
en |
dc.language |
English |
en |
dc.publisher |
American Chemical Society |
en |
dc.relation.ispartofseries |
Journal of the American Chemical Society |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0002-7863/
http://pubs.acs.org/page/policy/articlesonrequest/index.html |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.title |
Catalytic redistribution and polymerization of diborazanes: unexpected observation of metal-free hydrogen transfer between aminoboranes and amine-boranes |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1021/ja208752w |
en |
pubs.issue |
48 |
en |
pubs.begin-page |
19322 |
en |
pubs.volume |
133 |
en |
dc.description.version |
VoR - Version of Record |
en |
dc.identifier.pmid |
22035112 |
en |
pubs.author-url |
http://pubs.acs.org/doi/abs/10.1021/ja208752w |
en |
pubs.end-page |
19325 |
en |
pubs.publication-status |
Published |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
516192 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
dc.identifier.eissn |
1520-5126 |
en |
pubs.record-created-at-source-date |
2016-10-17 |
en |
pubs.online-publication-date |
2011-10-28 |
en |
pubs.dimensions-id |
22035112 |
en |