dc.contributor.author |
Daniels, BJ |
en |
dc.contributor.author |
Prijic, G |
en |
dc.contributor.author |
Meidinger, Sarah |
en |
dc.contributor.author |
Loomes, Kerry |
en |
dc.contributor.author |
Stephens, JM |
en |
dc.contributor.author |
Schlothauer, RC |
en |
dc.contributor.author |
Furkert, Daniel |
en |
dc.contributor.author |
Brimble, Margaret |
en |
dc.date.accessioned |
2017-02-06T23:00:33Z |
en |
dc.date.available |
2016-05-21 |
en |
dc.date.issued |
2016-06 |
en |
dc.identifier.citation |
Journal of Agricultural and Food Chemistry, Jun 2016, 64 (24), 5079 - 5084 |
en |
dc.identifier.issn |
0021-8561 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/31737 |
en |
dc.description.abstract |
Ma̅nuka honey, made from the nectar of Leptospermum scoparium, has garnered scientific and economical interest due to its nonperoxide antibacterial activity. Biomarkers for genuine ma̅nuka honey are increasingly in demand due to the presence of counterfeit ma̅nuka honey. This work reports the identification of a compound previously unreported in ma̅nuka honey by HPLC, and determination of the structure of the as 3,6,7-trimethyllumazine using NMR, MS, IR, and UV/vis spectroscopy. This assignment was confirmed by total synthesis. The natural product, renamed lepteridine, was only observed in ma̅nuka honeys and could potentially serve as a biomarker for genuine ma̅nuka honey. |
en |
dc.format.medium |
Print-Electronic |
en |
dc.language |
English |
en |
dc.publisher |
American Chemical Society |
en |
dc.relation.ispartofseries |
Journal of Agricultural and Food Chemistry |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0021-8561/
http://pubs.acs.org/page/copyright/index.html |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.title |
Isolation, Structural Elucidation, and Synthesis of Lepteridine From Manuka (Leptospermum scoparium) Honey |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1021/acs.jafc.6b01596 |
en |
pubs.issue |
24 |
en |
pubs.begin-page |
5079 |
en |
pubs.volume |
64 |
en |
dc.description.version |
VoR - Version of Record |
en |
dc.identifier.pmid |
27210444 |
en |
pubs.author-url |
http://pubs.acs.org/doi/abs/10.1021/acs.jafc.6b01596 |
en |
pubs.end-page |
5084 |
en |
pubs.publication-status |
Published |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
528984 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Biological Sciences |
en |
pubs.org-id |
Chemistry |
en |
pubs.org-id |
Science Research |
en |
pubs.org-id |
Maurice Wilkins Centre (2010-2014) |
en |
dc.identifier.eissn |
1520-5118 |
en |
pubs.record-created-at-source-date |
2017-02-07 |
en |
pubs.online-publication-date |
2016-05-22 |
en |
pubs.dimensions-id |
27210444 |
en |