Synthesis of tunichrome Sp-1

Pullar, MA; Barker, David; Copp, Brent

dc.contributor.author	Pullar, MA	en
dc.contributor.author	Barker, David	en
dc.contributor.author	Copp, Brent	en
dc.date.accessioned	2017-11-15T03:34:40Z	en
dc.date.available	2015-08-20	en
dc.date.issued	2015-10-07	en
dc.identifier.citation	Tetrahedron Letters, 56(41):5604-5606, 07 Oct 2015	en
dc.identifier.issn	0040-4039	en
dc.identifier.uri	http://hdl.handle.net/2292/36424	en
dc.description.abstract	The first total synthesis of the ascidian blood pigment tunichrome Sp-1 is reported, with the modified pentapeptide prepared in a convergent manner using a combination of solid-phase peptide synthesis, Hunsdiecker decarboxylative iodination and Buchwald amidation reaction chemistry. The natural product was shown to exist as a mixture of trans- and cis-prolyl conformers, with the former dominating in a 5:1 ratio.	en
dc.language	English	en
dc.publisher	Elsevier	en
dc.relation.ispartofseries	Tetrahedron Letters	en
dc.rights	Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://sherpa.ac.uk/romeo/issn/0040-4039/ https://www.elsevier.com/about/our-business/policies/sharing	en
dc.rights.uri	https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm	en
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/	en
dc.title	Synthesis of tunichrome Sp-1	en
dc.type	Journal Article	en
dc.identifier.doi	10.1016/j.tetlet.2015.08.047	en
pubs.issue	41	en
pubs.begin-page	5604	en
pubs.volume	56	en
dc.rights.holder	Copyright: Elsevier	en
pubs.author-url	http://www.sciencedirect.com/science/article/pii/S0040403915300022	en
pubs.declined	2017-09-03T19:17:41.660+1200	en
pubs.declined	2017-09-10T17:02:53.965+1200	en
pubs.end-page	5606	en
pubs.publication-status	Published	en
dc.rights.accessrights	http://purl.org/eprint/accessRights/OpenAccess	en
pubs.subtype	Article	en
pubs.elements-id	496297	en
pubs.org-id	Science	en
pubs.org-id	Chemistry	en
pubs.org-id	Science Research	en
pubs.org-id	Maurice Wilkins Centre (2010-2014)	en
dc.identifier.eissn	1873-3581	en
pubs.record-created-at-source-date	2017-10-19	en
pubs.online-publication-date	2015-08-21	en