Synthesis of tunichrome Sp-1

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dc.contributor.author Pullar, MA en
dc.contributor.author Barker, David en
dc.contributor.author Copp, Brent en
dc.date.accessioned 2017-11-15T03:34:40Z en
dc.date.available 2015-08-20 en
dc.date.issued 2015-10-07 en
dc.identifier.citation Tetrahedron Letters, 56(41):5604-5606, 07 Oct 2015 en
dc.identifier.issn 0040-4039 en
dc.identifier.uri http://hdl.handle.net/2292/36424 en
dc.description.abstract The first total synthesis of the ascidian blood pigment tunichrome Sp-1 is reported, with the modified pentapeptide prepared in a convergent manner using a combination of solid-phase peptide synthesis, Hunsdiecker decarboxylative iodination and Buchwald amidation reaction chemistry. The natural product was shown to exist as a mixture of trans- and cis-prolyl conformers, with the former dominating in a 5:1 ratio. en
dc.language English en
dc.publisher Elsevier en
dc.relation.ispartofseries Tetrahedron Letters en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://sherpa.ac.uk/romeo/issn/0040-4039/ https://www.elsevier.com/about/our-business/policies/sharing en
dc.rights.uri https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm en
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/4.0/ en
dc.title Synthesis of tunichrome Sp-1 en
dc.type Journal Article en
dc.identifier.doi 10.1016/j.tetlet.2015.08.047 en
pubs.issue 41 en
pubs.begin-page 5604 en
pubs.volume 56 en
dc.rights.holder Copyright: Elsevier en
pubs.author-url http://www.sciencedirect.com/science/article/pii/S0040403915300022 en
pubs.declined 2017-09-03T19:17:41.660+1200 en
pubs.declined 2017-09-10T17:02:53.965+1200 en
pubs.end-page 5606 en
pubs.publication-status Published en
dc.rights.accessrights http://purl.org/eprint/accessRights/OpenAccess en
pubs.subtype Article en
pubs.elements-id 496297 en
pubs.org-id Science en
pubs.org-id Chemistry en
pubs.org-id Science Research en
pubs.org-id Maurice Wilkins Centre (2010-2014) en
dc.identifier.eissn 1873-3581 en
pubs.record-created-at-source-date 2017-10-19 en
pubs.online-publication-date 2015-08-21 en


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