Recent Advances in the Synthesis, Characterization and Application of Zn+-containing Heterogeneous Catalysts.

Show simple item record Chen, Guangbo en Zhao, Yufei en Shang, Lu en Waterhouse, Geoffrey en Kang, Xiaofeng en Wu, Li-Zhu en Tung, Chen-Ho en Zhang, Tierui en 2018-10-16T03:28:37Z en 2016-07 en
dc.identifier.citation Advanced science 3(7):1500424 Jul 2016 en
dc.identifier.issn 2198-3844 en
dc.identifier.uri en
dc.description.abstract Monovalent Zn+ (3d104s1) systems possess a special electronic structure that can be exploited in heterogeneous catalysis and photocatalysis, though it remains challenge to synthesize Zn+-containing materials. By careful design, Zn+-related species can be synthesized in zeolite and layered double hydroxide systems, which in turn exhibit excellent catalytic potential in methane, CO and CO2 activation. Furthermore, by utilizing advanced characterization tools, including electron spin resonance, X-ray absorption fine structure and density functional theory calculations, the formation mechanism of the Zn+ species and their structure-performance relationships can be understood. Such advanced characterization tools guide the rational design of high-performance Zn+-containing catalysts for efficient energy conversion. en
dc.format.medium Electronic-eCollection en
dc.language eng en
dc.relation.ispartofseries Advanced science (Weinheim, Baden-Wurttemberg, Germany) en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. en
dc.rights.uri en
dc.rights.uri en
dc.title Recent Advances in the Synthesis, Characterization and Application of Zn+-containing Heterogeneous Catalysts. en
dc.type Journal Article en
dc.identifier.doi 10.1002/advs.201500424 en
pubs.issue 7 en
pubs.begin-page 1500424 en
pubs.volume 3 en
dc.rights.holder Copyright: The authors en
dc.identifier.pmid 27818902 en
pubs.publication-status Published en
dc.rights.accessrights en
pubs.subtype research-article en
pubs.subtype Journal Article en
pubs.elements-id 540792 en Science en Chemistry en
dc.identifier.eissn 2198-3844 en
pubs.record-created-at-source-date 2016-11-08 en
pubs.dimensions-id 27818902 en

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