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| dc.contributor.author | Lemon, Christopher M | en |
| dc.contributor.author | Powers, David C | en |
| dc.contributor.author | Brothers, Penelope | en |
| dc.contributor.author | Nocera, Daniel G | en |
| dc.date.accessioned | 2018-11-20T00:26:35Z | en |
| dc.date.issued | 2017-09-05 | en |
| dc.identifier.issn | 0020-1669 | en |
| dc.identifier.uri | http://hdl.handle.net/2292/44489 | en |
| dc.description.abstract | The triplet state of gold(III) corroles is exploited for optical oxygen sensing. We report intense phosphorescence for gold(III) corroles in the near-IR, an optical window that is ideal for tissue transparency. Moreover, the triplet excited-state emission exhibits significant changes in intensity and lifetime over the 0-160 Torr O2 pressure range. This renders these compounds sensitive at biologically relevant pressures and overcomes the spectral limitations of palladium and platinum porphyrins for oxygen sensing in biology. | en |
| dc.format.medium | Print-Electronic | en |
| dc.language | eng | en |
| dc.relation.ispartofseries | Inorganic chemistry | en |
| dc.rights | Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. | en |
| dc.rights.uri | https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm | en |
| dc.title | Gold Corroles as Near-IR Phosphors for Oxygen Sensing. | en |
| dc.type | Journal Article | en |
| dc.identifier.doi | 10.1021/acs.inorgchem.7b01302 | en |
| pubs.issue | 18 | en |
| pubs.begin-page | 10991 | en |
| pubs.volume | 56 | en |
| dc.rights.holder | Copyright: The author | en |
| dc.identifier.pmid | 28872307 | en |
| pubs.end-page | 10997 | en |
| pubs.publication-status | Published | en |
| dc.rights.accessrights | http://purl.org/eprint/accessRights/RestrictedAccess | en |
| pubs.subtype | Journal Article | en |
| pubs.elements-id | 667360 | en |
| pubs.org-id | Science | en |
| pubs.org-id | Chemistry | en |
| dc.identifier.eissn | 1520-510X | en |
| pubs.record-created-at-source-date | 2017-09-06 | en |
| pubs.dimensions-id | 28872307 | en |
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