dc.contributor.author |
Frogley, Benjamin J |
en |
dc.contributor.author |
Wright, Leonard |
en |
dc.date.accessioned |
2018-11-21T03:18:28Z |
en |
dc.date.issued |
2017-01 |
en |
dc.identifier.issn |
1433-7851 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/44515 |
en |
dc.description.abstract |
Metalla-analogues of archetypal aromatic molecules are attracting ever increasing interest. Although metallabenzenes (which fall within this class) have been well studied, fused-ring metallabenzenes are rare and of the linear polycyclic metallaaromatic hydrocarbons, only metallanaphthalene is known. Herein we report the first metallaanthracene, [Ir(C13 H8 {CH2 CO2 Me-5})Cl(PPh3 )2 ]O3 SCF3 (5), which represents the next member of this series of polycyclic compounds. Structurally, 5 has a number of features in common with anthracene including fused-ring planarity and bond-length alternation. In analogues of classic reactions of anthracene, 5 forms a Diels-Alder adduct with maleic anhydride and on oxidation the unprecedented fused-ring metallaanthraquinone, [Ir(C15 H6 O{Br-6}{OMe-7}{=O-8}{=O-15})Br(PPh3 )2 ], is obtained. |
en |
dc.format.medium |
Print-Electronic |
en |
dc.language |
eng |
en |
dc.relation.ispartofseries |
Angewandte Chemie (International ed. in English) |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.title |
A Metallaanthracene and Derived Metallaanthraquinone. |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1002/anie.201608500 |
en |
pubs.issue |
1 |
en |
pubs.begin-page |
143 |
en |
pubs.volume |
56 |
en |
dc.rights.holder |
Copyright: The author |
en |
dc.identifier.pmid |
27762094 |
en |
pubs.end-page |
147 |
en |
pubs.publication-status |
Published |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Research Support, Non-U.S. Gov't |
en |
pubs.subtype |
Journal Article |
en |
pubs.elements-id |
544165 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
dc.identifier.eissn |
1521-3773 |
en |
pubs.record-created-at-source-date |
2016-10-20 |
en |
pubs.dimensions-id |
27762094 |
en |