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| dc.contributor.author | Badrinarayanan, Sandhya | en |
| dc.contributor.author | Squire, Christopher | en |
| dc.contributor.author | Sperry, Jonathan | en |
| dc.contributor.author | Brimble, Margaret | en |
| dc.date.accessioned | 2018-11-21T21:19:39Z | en |
| dc.date.issued | 2017-07 | en |
| dc.identifier.issn | 1523-7060 | en |
| dc.identifier.uri | http://hdl.handle.net/2292/44525 | en |
| dc.description.abstract | The total synthesis of both enantiomers of pestalospirane B, 2, has been achieved using a bioinspired tandem dimerization-spiroketalization reaction. Electronic circular dichroism (ECD) and X-ray analysis were used to revise the absolute stereochemistry of the natural product pestalospirane B from 3S, 3'S, 12R, 12'R to its enantiomer 3R, 3'R, 12S, 12'S. | en |
| dc.format.medium | Print-Electronic | en |
| dc.language | eng | en |
| dc.relation.ispartofseries | Organic letters | en |
| dc.rights | Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. | en |
| dc.rights.uri | https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm | en |
| dc.subject | Xanthophylls | en |
| dc.subject | Benzoxepins | en |
| dc.subject | Spiro Compounds | en |
| dc.subject | Circular Dichroism | en |
| dc.subject | Molecular Structure | en |
| dc.subject | Stereoisomerism | en |
| dc.title | Bioinspired Total Synthesis and Stereochemical Revision of the Fungal Metabolite Pestalospirane B. | en |
| dc.type | Journal Article | en |
| dc.identifier.doi | 10.1021/acs.orglett.7b01371 | en |
| pubs.issue | 13 | en |
| pubs.begin-page | 3414 | en |
| pubs.volume | 19 | en |
| dc.rights.holder | Copyright: The author | en |
| dc.identifier.pmid | 28621951 | en |
| pubs.end-page | 3417 | en |
| pubs.publication-status | Published | en |
| dc.rights.accessrights | http://purl.org/eprint/accessRights/RestrictedAccess | en |
| pubs.subtype | Research Support, Non-U.S. Gov't | en |
| pubs.subtype | Journal Article | en |
| pubs.elements-id | 632440 | en |
| pubs.org-id | Science | en |
| pubs.org-id | Biological Sciences | en |
| pubs.org-id | Chemistry | en |
| pubs.org-id | Science Research | en |
| pubs.org-id | Maurice Wilkins Centre (2010-2014) | en |
| dc.identifier.eissn | 1523-7052 | en |
| pubs.record-created-at-source-date | 2017-06-17 | en |
| pubs.dimensions-id | 28621951 | en |
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