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| dc.contributor.author | Ludvíková, Lucie | en |
| dc.contributor.author | Štacko, Peter | en |
| dc.contributor.author | Sperry, Jonathan | en |
| dc.contributor.author | Klán, Petr | en |
| dc.date.accessioned | 2019-02-28T21:41:52Z | en |
| dc.date.issued | 2018-09 | en |
| dc.identifier.issn | 0022-3263 | en |
| dc.identifier.uri | http://hdl.handle.net/2292/45634 | en |
| dc.description.abstract | Photosensitized cross-linking of N-acetyl derivatives of tryptophan and tyrosine by rose bengal in phosphate buffer saline was studied by steady-state absorption and emission spectroscopy, nanosecond transient absorption spectroscopy, and chemical analyses. These amino acids undergo cross-linking to form dimeric and higher oligomeric products under anoxic conditions with rose bengal as a sacrificial oxidant, whereas they react predominantly with singlet oxygen produced by rose bengal in aerated solutions. This investigation provides a comprehensive view into the first steps of rose bengal photosensitized cross-linking of these two amino acids. The results can be helpful for future applications of rose bengal and related dyes, such as photochemical tissue bonding or visible light photocatalysis. | en |
| dc.format.medium | Print-Electronic | en |
| dc.language | eng | en |
| dc.relation.ispartofseries | The Journal of organic chemistry | en |
| dc.rights | Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. | en |
| dc.rights.uri | https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm | en |
| dc.title | Photosensitized Cross-Linking of Tryptophan and Tyrosine Derivatives by Rose Bengal in Aqueous Solutions. | en |
| dc.type | Journal Article | en |
| dc.identifier.doi | 10.1021/acs.joc.8b01545 | en |
| pubs.issue | 18 | en |
| pubs.begin-page | 10835 | en |
| pubs.volume | 83 | en |
| dc.rights.holder | Copyright: The author | en |
| pubs.end-page | 10844 | en |
| pubs.publication-status | Published | en |
| dc.rights.accessrights | http://purl.org/eprint/accessRights/RestrictedAccess | en |
| pubs.subtype | Research Support, Non-U.S. Gov't | en |
| pubs.subtype | Journal Article | en |
| pubs.elements-id | 751943 | en |
| pubs.org-id | Science | en |
| pubs.org-id | Chemistry | en |
| dc.identifier.eissn | 1520-6904 | en |
| pubs.record-created-at-source-date | 2018-08-08 | en |
| pubs.dimensions-id | 30085660 | en |
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