Mechanochemical Studies Towards Adipic Acid from Biomass

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dc.contributor.advisor Sperry, J en
dc.contributor.author Russell, Emily en
dc.date.accessioned 2019-08-19T02:59:31Z en
dc.date.issued 2019 en
dc.identifier.uri http://hdl.handle.net/2292/47508 en
dc.description Full Text is available to authenticated members of The University of Auckland only. en
dc.description.abstract This thesis describes synthetic studies towards the mechanochemical synthesis of the commodity chemical adipic acid from biomass-derived platform chemicals. The current process for adipic acid production is inefficient due to the use of toxic starting materials derived from limited fossil resources, as well as the production of large amounts of greenhouse gas by products. As an alternative, we propose that a new synthetic route to adipic acid can be achieved mechanochemically, transforming sustainable, biomass-derived platform chemicals into a valuable commodity, in the solid state. The mechanochemical synthesis of adipic acid was attempted from cyclopentanone, a lignocellulose-derived platform chemical, and mucic acid, a dicarboxylic acid derived from carbohydrates, but both routes were plagued with difficulties. Despite significant investigation, both routes proved unsuccessful under all conditions tried, highlighting the necessity for stable reagents and substrates under mechanochemical conditions. Although adipic acid was not attained within the time-frame of this project, several interesting results were discovered that emphasise the potential of mechanochemistry in organic chemistry. en
dc.publisher ResearchSpace@Auckland en
dc.relation.ispartof Masters Thesis - University of Auckland en
dc.relation.isreferencedby UoA99265170013902091 en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. en
dc.rights Restricted Item. Full Text is available to authenticated members of The University of Auckland only. en
dc.rights.uri https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm en
dc.rights.uri http://creativecommons.org/licenses/by-nc-sa/3.0/nz/ en
dc.title Mechanochemical Studies Towards Adipic Acid from Biomass en
dc.type Thesis en
thesis.degree.discipline Chemistry en
thesis.degree.grantor The University of Auckland en
thesis.degree.level Masters en
dc.rights.holder Copyright: The author en
pubs.elements-id 779213 en
pubs.record-created-at-source-date 2019-08-19 en


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