Quinoline-para-quinones and metals: coordination-assisted formation of quinoline-ortho-quinones.

Kubanik, Mario; Lam, Nelson YS; Holtkamp, Hannah U; Söhnel, Tilo; Anderson, Robert F; Jamieson, Stephen MF; Hartinger, Christian G

Quinoline-para-quinones and metals: coordination-assisted formation of quinoline-ortho-quinones.

Kubanik, Mario ; Lam, Nelson YS ; Holtkamp, Hannah U ; Söhnel, Tilo ; Anderson, Robert F ; Jamieson, Stephen MF ; Hartinger, Christian G

Identifier: http://hdl.handle.net/2292/53840

Issue Date: 2018-1

Reference: Chemical communications (Cambridge, England) 54(8):992-995 Jan 2018

Rights: Copyright: Royal Society of Chemistry

Rights (URI): https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm

Abstract:

The reaction of the para-quinone 6,7-dichloroquinoline-5,8-dione with various transition metal dimers led to the unexpected formation of quinoline-ortho-quinone metal complexes. Systematic variation of the reaction conditions helped identify the solvent as the source of the carbonyl oxygen.

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