dc.contributor.author |
Mosaferi, Shabnam |
|
dc.contributor.author |
Jelley, Rebecca E |
|
dc.contributor.author |
Fedrizzi, Bruno |
|
dc.contributor.author |
Barker, David |
|
dc.date.accessioned |
2021-10-05T06:15:58Z |
|
dc.date.available |
2021-10-05T06:15:58Z |
|
dc.date.issued |
2020-12-1 |
|
dc.identifier.issn |
0040-4039 |
|
dc.identifier.uri |
https://hdl.handle.net/2292/56790 |
|
dc.description.abstract |
C13 Norisoprenoids are important aroma compounds in wine, giving positive attributes to the overall wine aroma even when found at very low levels. β-Ionone is considered one of the most important aroma compounds giving violet, woody and raspberry aromas to wine, fruits and vegetables in which it is found. Due to its potent aroma at low levels, precise analytical methods are desired for its quantification. Stable isotope dilution assay (SIDA) is one of the most important of these methods but requires the use of isotopically labelled standards. Herein, we describe the scalable synthesis of d6-β-ionone and d6-β-cyclocitral, another aroma compound with smokey and fruity notes, starting from the relatively inexpensive deuterated starting material d6-acetone. |
|
dc.language |
en |
|
dc.publisher |
Elsevier BV |
|
dc.relation.ispartofseries |
Tetrahedron Letters |
|
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. |
|
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
|
dc.subject |
Science & Technology |
|
dc.subject |
Physical Sciences |
|
dc.subject |
Chemistry, Organic |
|
dc.subject |
Chemistry |
|
dc.subject |
Aroma compounds |
|
dc.subject |
Labelled standards |
|
dc.subject |
beta-lonone |
|
dc.subject |
Stable isotope dilution assays |
|
dc.subject |
VARIETAL AROMA |
|
dc.subject |
RED WINES |
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dc.subject |
BETA-IONONE |
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dc.subject |
QUANTIFICATION |
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dc.subject |
GRAPES |
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dc.subject |
PRECURSORS |
|
dc.subject |
FERMENTATION |
|
dc.subject |
EXTRACTION |
|
dc.subject |
VOLATILES |
|
dc.subject |
IMPACT |
|
dc.subject |
0304 Medicinal and Biomolecular Chemistry |
|
dc.subject |
0305 Organic Chemistry |
|
dc.title |
Scalable synthesis of the aroma compounds d6-β-ionone and d6-β-cyclocitral for use as internal standards in stable isotope dilution assays |
|
dc.type |
Journal Article |
|
dc.identifier.doi |
10.1016/j.tetlet.2020.152642 |
|
pubs.issue |
51 |
|
pubs.begin-page |
152642 |
|
pubs.volume |
61 |
|
dc.date.updated |
2021-09-18T22:35:26Z |
|
dc.rights.holder |
Copyright: The author |
en |
pubs.author-url |
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000594329900011&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=6e41486220adb198d0efde5a3b153e7d |
|
pubs.publication-status |
Published |
|
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
|
pubs.subtype |
Journal |
|
pubs.elements-id |
830557 |
|
dc.identifier.eissn |
1873-3581 |
|
pubs.number |
152642 |
|