The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline.

Zujovic, Zoran; Kilmartin, Paul A; Travas-Sejdic, Jadranka

dc.contributor.author	Zujovic, Zoran
dc.contributor.author	Kilmartin, Paul A
dc.contributor.author	Travas-Sejdic, Jadranka
dc.coverage.spatial	Switzerland
dc.date.accessioned	2022-10-27T23:24:28Z
dc.date.available	2022-10-27T23:24:28Z
dc.date.issued	2020-01-21
dc.identifier.citation	(2020). Molecules, 25(3), E444-.
dc.identifier.issn	1420-3049
dc.identifier.uri	https://hdl.handle.net/2292/61711
dc.description.abstract	Polyaniline is one of the most well studied conducting polymers due to its advanced electrical, chemical, redox and morphological properties. The high conductivity of regular polyaniline, when partially oxidized and doped under acidic conditions, has been associated with the formation of unique electronic states known as polarons and bipolarons. Alternative aniline oxidation products and interesting nanotube and nanorod forms have been observed as the synthesis conditions are varied. Solid-state NMR has offered great opportunities for structural investigations and the determination of molecular dynamics in such a complex and diverse material. This review summarizes various applications of solid-state NMR techniques to polyaniline and its derivatives and the information that can be obtained by solid-state NMR.
dc.format.medium	Electronic
dc.language	eng
dc.publisher	MDPI
dc.relation.ispartofseries	Molecules (Basel, Switzerland)
dc.rights	Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher.
dc.rights.uri	https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/
dc.subject	Aniline Compounds
dc.subject	Polymers
dc.subject	Magnetic Resonance Spectroscopy
dc.subject	Temperature
dc.subject	Oxidation-Reduction
dc.subject	Electric Conductivity
dc.subject	bipolarons
dc.subject	conducting polymers
dc.subject	conductivity
dc.subject	emeraldine salt
dc.subject	mechanism
dc.subject	polarons
dc.subject	polyaniline
dc.subject	solid-state NMR
dc.subject	Science & Technology
dc.subject	Life Sciences & Biomedicine
dc.subject	Physical Sciences
dc.subject	Biochemistry & Molecular Biology
dc.subject	Chemistry, Multidisciplinary
dc.subject	Chemistry
dc.subject	ACID-DOPED POLYANILINE
dc.subject	GEL-PERMEATION CHROMATOGRAPHY
dc.subject	NUCLEAR-MAGNETIC-RESONANCE
dc.subject	C-13 NMR
dc.subject	N-15 NMR
dc.subject	ELECTRICAL-CONDUCTIVITY
dc.subject	MOLECULAR-WEIGHTS
dc.subject	ANILINE OLIGOMERS
dc.subject	CPMAS NMR
dc.subject	CP-MAS
dc.subject	0306 Physical Chemistry (incl. Structural)
dc.subject	0303 Macromolecular and Materials Chemistry
dc.subject	0304 Medicinal and Biomolecular Chemistry
dc.subject	0305 Organic Chemistry
dc.subject	0307 Theoretical and Computational Chemistry
dc.title	The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline.
dc.type	Journal Article
dc.identifier.doi	10.3390/molecules25030444
pubs.issue	3
pubs.begin-page	E444
pubs.volume	25
dc.date.updated	2022-09-30T04:52:57Z
dc.rights.holder	Copyright: The authors	en
dc.identifier.pmid	31973166 (pubmed)
pubs.author-url	https://www.ncbi.nlm.nih.gov/pubmed/31973166
pubs.publication-status	Published
dc.rights.accessrights	http://purl.org/eprint/accessRights/OpenAccess	en
pubs.subtype	IM
pubs.subtype	review-article
pubs.subtype	Review
pubs.subtype	Journal Article
pubs.elements-id	793637
pubs.org-id	Science
pubs.org-id	Chemistry
dc.identifier.eissn	1420-3049
dc.identifier.pii	molecules25030444
pubs.number	ARTN 444
pubs.record-created-at-source-date	2022-09-30
pubs.online-publication-date	2020-01-21