A Ring Closing Metathesis Approach to the Formal Synthesis of (+)‐Callyspongiolide

Ko, Kwang‐Yoon; Wilson, Zoe E; Furkert, Daniel P; Brimble, Margaret A

dc.contributor.author	Ko, Kwang‐Yoon
dc.contributor.author	Wilson, Zoe E
dc.contributor.author	Furkert, Daniel P
dc.contributor.author	Brimble, Margaret A
dc.date.accessioned	2023-07-10T04:28:43Z
dc.date.available	2023-07-10T04:28:43Z
dc.date.issued	2020-11-19
dc.identifier.citation	(2020). ChemCatChem, 12(22), 5759-5771.
dc.identifier.issn	1867-3880
dc.identifier.uri	https://hdl.handle.net/2292/64611
dc.description.abstract	An enantioselective synthesis of macrocyclic core of (+)-callyspongiolide is described, constituting a formal synthesis of this natural product. The synthetic strategy constructs the 14-membered macrocyclic domain via Yamaguchi esterification followed by a challenging ring-closing metathesis (RCM) to effect the final formation of the macrolactone.
dc.language	en
dc.publisher	Wiley
dc.relation.ispartofseries	ChemCatChem
dc.rights	Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher.
dc.rights.uri	https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm
dc.subject	Science & Technology
dc.subject	Physical Sciences
dc.subject	Chemistry, Physical
dc.subject	Chemistry
dc.subject	callyspongiolide
dc.subject	homocrotylation
dc.subject	natural product
dc.subject	ring closing metathesis
dc.subject	Yamaguchi esterification
dc.subject	ENANTIOSELECTIVE TOTAL-SYNTHESIS
dc.subject	RED-SEA SPONGE
dc.subject	MARINE SPONGE
dc.subject	STRUCTURAL ASSIGNMENT
dc.subject	CYTOTOXIC MACROLIDE
dc.subject	SELECTIVE SYNTHESIS
dc.subject	UNSATURATED ESTERS
dc.subject	FRAGMENT
dc.subject	HOMOCROTYLBORATION
dc.subject	0302 Inorganic Chemistry
dc.subject	0306 Physical Chemistry (incl. Structural)
dc.subject	0904 Chemical Engineering
dc.title	A Ring Closing Metathesis Approach to the Formal Synthesis of (+)‐Callyspongiolide
dc.type	Journal Article
dc.identifier.doi	10.1002/cctc.202001139
pubs.issue	22
pubs.begin-page	5759
pubs.volume	12
dc.date.updated	2023-06-29T00:34:25Z
dc.rights.holder	Copyright: The authors	en
pubs.author-url	http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000566542500001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=6e41486220adb198d0efde5a3b153e7d
pubs.end-page	5771
pubs.publication-status	Published
dc.rights.accessrights	http://purl.org/eprint/accessRights/RetrictedAccess	en
pubs.subtype	Article
pubs.subtype	Journal
pubs.elements-id	816320
pubs.org-id	Science
pubs.org-id	Chemistry
pubs.org-id	Science Research
pubs.org-id	Maurice Wilkins Centre (2010-2014)
dc.identifier.eissn	1867-3899
pubs.record-created-at-source-date	2023-06-29
pubs.online-publication-date	2020-09-07