Sol-enhanced nanostructured metal-oxide composite coatings: structures, properties and mechanisms

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dc.contributor.advisor Gao, W en
dc.contributor.author Chen, Weiwei en
dc.date.accessioned 2011-03-15T03:18:43Z en
dc.date.issued 2010 en
dc.identifier.uri http://hdl.handle.net/2292/6620 en
dc.description.abstract In the present research, a novel sol-enhanced electro- or electroless deposition processs has been developed to prepare composite coatings reinforced by highly dispersive nano-particles. A transparent TiO₂ sol was added into the traditional electro-/electrless plating Ni electrolyte. The TiO₂ nano-particles in situ formed, and then co-deposited with Ni atoms to form highly dispersive TiO₂ nano-particles reinforced Ni-based composite coatings. Two electrochemical deposition systems, i.e. electro- and electroless plating, were used in this thesis to synthesize sol-enhanced electroless plated Ni-P-TiO₂ and electroplated Ni-TiO₂ composite coatings. The objective of the research in the thesis was to understand the formation mechanism and electrochemical behaviours of the sol-enhanced composite coatings; to investigate the effect of highly dispersive nano-particles on the mechanical/physical properties and corrosion resistance of composite coatings. The research was started with an investigation of the processing of sol-enhanced electroless plated Ni-P-TiO₂ composite coatings. Then systematic investigations were conducted on sol-enhanced electroplated Ni-TiO₂ composite coatings based on three aspects: the effect of the sol concentration, the electrochemical process, and the thermal stability & tensile properties. en
dc.publisher ResearchSpace@Auckland en
dc.relation.ispartof PhD Thesis - University of Auckland en
dc.relation.isreferencedby UoA99210993414002091 en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. en
dc.rights.uri https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm en
dc.rights.uri http://creativecommons.org/licenses/by-nc-sa/3.0/nz/ en
dc.title Sol-enhanced nanostructured metal-oxide composite coatings: structures, properties and mechanisms en
dc.type Thesis en
thesis.degree.discipline Chemical and Materials Engineering en
thesis.degree.grantor The University of Auckland en
thesis.degree.level Doctoral en
thesis.degree.name PhD en
dc.rights.holder Copyright: The author en
pubs.elements-id 207264 en
pubs.record-created-at-source-date 2011-03-15 en


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http://creativecommons.org/licenses/by-nc-sa/3.0/nz/ Except where otherwise noted, this item's license is described as http://creativecommons.org/licenses/by-nc-sa/3.0/nz/

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