dc.contributor.author |
Weihs, D |
|
dc.contributor.author |
Kesselman, E |
|
dc.contributor.author |
Schmidt, J |
|
dc.contributor.author |
Talmon, Y |
|
dc.contributor.author |
Sasuga, S |
|
dc.contributor.author |
Fujita, T |
|
dc.contributor.author |
Izawa, K-I |
|
dc.contributor.author |
O'Connor, CJ |
|
dc.contributor.author |
Okabayashi, H-F |
|
dc.coverage.spatial |
United States |
|
dc.date.accessioned |
2023-12-14T02:29:35Z |
|
dc.date.available |
2023-12-14T02:29:35Z |
|
dc.date.issued |
2017-04-14 |
|
dc.identifier.citation |
(2017). The Journal of Physical Chemistry B: Biophysical Chemistry, Biomaterials, Liquids, and Soft Matter, 121(16), 4099-4114. |
|
dc.identifier.issn |
1520-6106 |
|
dc.identifier.uri |
https://hdl.handle.net/2292/66938 |
|
dc.description.abstract |
For extremely asymmetric n-hexyl(n-decyl)phosphate (HDeP), n-hexyl(n-dodecyl)phosphate (HDoP), and n-hexyl(n-cetyl)phosphate (HCeP), the effect of the long-chains on the dynamic behavior of their aggregate structures in water was examined by cryo-TEM imaging, SANS, and X-ray diffraction techniques. The cryo-TEM images demonstrated the complex and dynamic behavior of the aggregates, and its dependence on the length of the long-chain. Application of the one-dimensional aggregate theory to the SANS results led to the conclusion that the existence of a limiting size also depended on the length of the main long-hydrocarbon chain and affected strongly the dynamic behavior of the aggregates, causing breakage of thread-like micelles or ribbon-like aggregates. The X-ray diffraction patterns of the lyotropic liquid crystalline samples of HDeP and HCeP were used to estimate the aggregate structures of this limited size. |
|
dc.format.medium |
Print-Electronic |
|
dc.language |
eng |
|
dc.publisher |
American Chemical Society (ACS) |
|
dc.relation.ispartofseries |
The Journal of Physical Chemistry. B |
|
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. |
|
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
|
dc.subject |
3403 Macromolecular and Materials Chemistry |
|
dc.subject |
34 Chemical Sciences |
|
dc.subject |
Science & Technology |
|
dc.subject |
Physical Sciences |
|
dc.subject |
Chemistry, Physical |
|
dc.subject |
Chemistry |
|
dc.subject |
ANGLE NEUTRON-SCATTERING |
|
dc.subject |
RAMAN-SCATTERING |
|
dc.subject |
ALKYL PHOSPHATES |
|
dc.subject |
LAMELLAR PHASES |
|
dc.subject |
WATER-SYSTEM |
|
dc.subject |
C-13 NMR |
|
dc.subject |
VESICLES |
|
dc.subject |
MICELLES |
|
dc.subject |
MICROEMULSION |
|
dc.subject |
TRANSITION |
|
dc.subject |
0303 Macromolecular and Materials Chemistry |
|
dc.subject |
02 Physical Sciences |
|
dc.subject |
03 Chemical Sciences |
|
dc.subject |
09 Engineering |
|
dc.subject |
40 Engineering |
|
dc.subject |
51 Physical sciences |
|
dc.title |
Complex, dynamic behavior of extremely Asymmetric Di-n-Alkylphosphate-Anion Aggregates, the long-chain effect and the role of a limiting size: Cryo-TEM, SANS, and X-Ray diffraction studies |
|
dc.type |
Journal Article |
|
dc.identifier.doi |
10.1021/acs.jpcb.7b00433 |
|
pubs.issue |
16 |
|
pubs.begin-page |
4099 |
|
pubs.volume |
121 |
|
dc.date.updated |
2023-11-05T14:27:11Z |
|
dc.rights.holder |
Copyright: American Chemical Society |
en |
dc.identifier.pmid |
28409927 (pubmed) |
|
pubs.author-url |
https://pubs.acs.org/doi/abs/10.1021/acs.jpcb.7b00433 |
|
pubs.end-page |
4114 |
|
pubs.publication-status |
Published |
|
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RetrictedAccess |
en |
pubs.subtype |
Article |
|
pubs.elements-id |
628303 |
|
pubs.org-id |
Science |
|
pubs.org-id |
Chemistry |
|
dc.identifier.eissn |
1520-5207 |
|
pubs.record-created-at-source-date |
2023-11-06 |
|
pubs.online-publication-date |
2017-04-14 |
|