dc.contributor.author |
Brothers, Penelope |
en |
dc.date.accessioned |
2011-08-05T04:44:47Z |
en |
dc.date.issued |
2008 |
en |
dc.identifier.citation |
Chemical Communications 2090-2102 2008 |
en |
dc.identifier.issn |
1359-7345 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/7197 |
en |
dc.description.abstract |
The coordination of boron to a range of polypyrrole-containing ligands is explored in this feature article. The boron dipyrromethenes are well-known as laser dyes and fluorescent labels in biology. Subphthalocyanine and subporphyrin macrocycles containing only three pyrrole rings can exist only when templated by a central boron atom. Boron complexes of expanded porphyrins ( six or eight pyrroles) can complex boron in dipyrromethene ( but not bipyrrole) sites. The primary focus of the article is on boron porphyrin and corrole complexes, where the tight fit of two boron atoms within the very constrained coordination site gives rise to unexpected chemistry at both boron and the porphyrin ligand. These unusual features are described and reasons for their occurrence postulated. |
en |
dc.language |
EN |
en |
dc.publisher |
ROYAL SOC CHEMISTRY |
en |
dc.relation.ispartofseries |
Chemical Communications |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/1359-7345// |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.subject |
N-CONFUSED PORPHYRIN |
en |
dc.subject |
CRYSTAL-STRUCTURE |
en |
dc.subject |
SPECTROSCOPIC PROPERTIES |
en |
dc.subject |
COORDINATION CHEMISTRY |
en |
dc.subject |
EXPANDED PORPHYRINS |
en |
dc.subject |
FUSED PORPHYRIN |
en |
dc.subject |
ENERGY-TRANSFER |
en |
dc.subject |
SUBPHTHALOCYANINE |
en |
dc.subject |
SUBPORPHYRINS |
en |
dc.subject |
BEARING |
en |
dc.title |
Boron complexes of porphyrins and related polypyrrole ligands: unexpected chemistry for both boron and the porphyrin. |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1039/b714894a |
en |
pubs.issue |
18 |
en |
pubs.begin-page |
2090 |
en |
dc.rights.holder |
Copyright: 2008 The Royal Society of Chemistry |
en |
dc.identifier.pmid |
18438481 |
en |
pubs.end-page |
2102 |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
84838 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
pubs.record-created-at-source-date |
2010-09-01 |
en |
pubs.dimensions-id |
18438481 |
en |