dc.contributor.author |
Albrett, AM |
en |
dc.contributor.author |
Boyd, Peter |
en |
dc.contributor.author |
Clark, George |
en |
dc.contributor.author |
Gonzalez, E |
en |
dc.contributor.author |
Ghosh, A |
en |
dc.contributor.author |
Brothers, Penelope |
en |
dc.date.accessioned |
2011-08-05T05:02:46Z |
en |
dc.date.issued |
2010 |
en |
dc.identifier.citation |
Dalton Trans. 39(17):4032-4034 2010 |
en |
dc.identifier.issn |
1477-9226 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/7199 |
en |
dc.description.abstract |
The reaction of PhBCl2 with free base triarylcorroles results in a spontaneous reduction to give diboron corrole complexes (PhBHBPh)(Cor) in which a proton has been captured to forma bridgingB-H-B group encapsulated within the corrole ligand. The proposed mechanism is supported by the reaction of PhBF2 with H(3)Cor to give (PhBF)(BPh)(Cor) in which no reduction has occurred. |
en |
dc.language |
EN |
en |
dc.publisher |
ROYAL SOC CHEMISTRY |
en |
dc.relation.ispartofseries |
Dalton Trans. |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/1477-9226// |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.subject |
PORPHYRIN COMPLEXES |
en |
dc.subject |
BINUCLEATING LIGAND |
en |
dc.subject |
CHEMISTRY |
en |
dc.subject |
BORON |
en |
dc.title |
Reductive coupling and protonation leading to diboron corroles with a B-H-B bridge |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1039/c002885c |
en |
pubs.issue |
17 |
en |
pubs.begin-page |
4032 |
en |
pubs.volume |
39 |
en |
dc.rights.holder |
Copyright: 2010 The Royal Society of Chemistry |
en |
dc.identifier.pmid |
20390165 |
en |
pubs.end-page |
4034 |
en |
pubs.publication-status |
Published |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
102706 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
pubs.record-created-at-source-date |
2010-09-01 |
en |
pubs.dimensions-id |
20390165 |
en |