Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: A terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions

Boyd, Peter; Edwards, AJ; Gardiner, MG; Ho, CC; Lemée-Cailleau, MH; McGuinness, DS; Riapanitra, A; Steed, JW; Stringer, DN; Yates, BF

dc.contributor.author	Boyd, Peter	en
dc.contributor.author	Edwards, AJ	en
dc.contributor.author	Gardiner, MG	en
dc.contributor.author	Ho, CC	en
dc.contributor.author	Lemée-Cailleau, MH	en
dc.contributor.author	McGuinness, DS	en
dc.contributor.author	Riapanitra, A	en
dc.contributor.author	Steed, JW	en
dc.contributor.author	Stringer, DN	en
dc.contributor.author	Yates, BF	en
dc.date.accessioned	2011-09-06T02:00:34Z	en
dc.date.issued	2010	en
dc.identifier.citation	ANGEW CHEM INT EDIT 49(36):6315-6318 2010	en
dc.identifier.issn	1433-7851	en
dc.identifier.uri	http://hdl.handle.net/2292/7698	en
dc.description.abstract	Keywords: coupling reactions;homogeneous catalysis;N-heterocyclic carbenes;palladium;reduction Half-way house: The first palladium(I) N-heterocyclic carbene complex has been isolated in high yield by the base-assisted reduction of a palladium(II) precursor. The location of the unique terminal hydride (see picture; PdI cyan, H white, N blue) was established by neutron crystal structure determination, and the solution fluxional behavior of the complex was explored.	en
dc.language	EN	en
dc.publisher	WILEY-V C H VERLAG GMBH	en
dc.relation.ispartofseries	Angewandte Chemie - International Edition	en
dc.rights	Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/1433-7851/	en
dc.rights.uri	https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm	en
dc.subject	coupling reactions	en
dc.subject	homogeneous catalysis	en
dc.subject	N-heterocyclic carbenes	en
dc.subject	palladium	en
dc.subject	reduction	en
dc.subject	N-HETEROCYCLIC CARBENES	en
dc.subject	CROSS-COUPLING REACTIONS	en
dc.subject	MIZOROKI-HECK REACTION	en
dc.subject	OXIDATIVE ADDITION	en
dc.subject	IMIDAZOLIUM SALTS	en
dc.subject	ARYL CHLORIDES	en
dc.subject	STRUCTURAL-CHARACTERIZATION	en
dc.subject	CATALYSTS	en
dc.subject	PD	en
dc.subject	REACTIVITY	en
dc.title	Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: A terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions	en
dc.type	Journal Article	en
dc.identifier.doi	10.1002/anie.201003177	en
pubs.issue	36	en
pubs.begin-page	6315	en
pubs.volume	49	en
dc.rights.holder	Copyright: 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim	en
dc.identifier.pmid	20737461	en
pubs.end-page	6318	en
pubs.publication-status	Published	en
dc.rights.accessrights	http://purl.org/eprint/accessRights/RestrictedAccess	en
pubs.subtype	Article	en
pubs.elements-id	150561	en
pubs.record-created-at-source-date	2010-09-28	en
pubs.dimensions-id	20737461	en