dc.contributor.author |
Blaser, Adrian |
en |
dc.contributor.author |
Boyd, Peter |
en |
dc.date.accessioned |
2011-09-06T02:21:19Z |
en |
dc.date.issued |
2008-09 |
en |
dc.identifier.citation |
ACTA CRYSTALLOGR E 64:O1851-U2780 Sep 2008 |
en |
dc.identifier.issn |
1600-5368 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/7742 |
en |
dc.description.abstract |
The title compound, C14H19NO3, was obtained as one of the two isomers of a Sharpless asymmetric dihydroxylation reaction of (1S)-1-[(1R)-1-phenylethyl]-4-vinylpyrrolidin-2-one. The absolute stereochemistry of this isomer was determined from the known stereochemistry (R) at the bridge C atom between the phenyl and pyrrolidine rings. The molecules form one-dimensional tapes along the b axis via hydrogen bonding between the carbonyl O atom and the alcohol groups of neighbouring molecules. These assemble into sheets via interdigitative stacking of the phenyl rings and C-H center dot center dot center dot O interactions. |
en |
dc.language |
EN |
en |
dc.publisher |
WILEY-BLACKWELL PUBLISHING, INC |
en |
dc.relation.ispartofseries |
ACTA CRYSTALLOGR E |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/1600-5368/ |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.rights.uri |
http://journals.iucr.org/services/copyrightpolicy.html |
en |
dc.title |
(4R)-4-[(1R)-1,2-dihydroxyethyl]-1-[(1R)-1-phenylethyl]pyrrolidin-2-one |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1107/S1600536808027293 |
en |
pubs.begin-page |
O1851 |
en |
pubs.volume |
64 |
en |
dc.rights.holder |
Copyright:2008 International Union of Crystallography |
en |
dc.identifier.pmid |
21201822 |
en |
pubs.end-page |
U2780 |
en |
pubs.publication-status |
Published |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/OpenAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
115848 |
en |
pubs.org-id |
Medical and Health Sciences |
en |
pubs.org-id |
Medical Sciences |
en |
pubs.org-id |
Auckland Cancer Research |
en |
pubs.record-created-at-source-date |
2010-09-28 |
en |
pubs.dimensions-id |
21201822 |
en |