Bis(N,N-diethyl-dithio-carbamato)(1,10-phenanthroline)cobalt(III) tetra-fluorido-borate

Boyd, Peter; Rickard, CEF

Bis(N,N-diethyl-dithio-carbamato)(1,10-phenanthroline)cobalt(III) tetra-fluorido-borate

Boyd, Peter ; Rickard, CEF

Identifier: http://hdl.handle.net/2292/7745

Issue Date: 2008

Reference: Acta Crystallographica Section E Structure Reports Online 64(7):m917-m918

Rights: Copyright: International Union of Crystallography

Rights (URI): https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm
Rights (URI): http://journals.iucr.org/services/copyrightpolicy.html

Abstract:

The cationic complex in the structure of the title compound, [Co(Et2NCS2)(2)(C12H8N2)] BF4, has a Co-III atom with a distorted octahedral coordination formed by four S atoms of two diethyldithiocarbamate and two N atoms of 1,10-phenanthroline ligands. The crystal structure features head-to-tail stacking of the phenanthroline ligands. The tetra-fluoridoborate anions are positioned in the channels between the cation stacks running along the a axis, and form weak C-H center dot center dot center dot F interactions.

Show full item record