dc.contributor.author |
crimmins, D |
en |
dc.contributor.author |
Choi, Ka |
en |
dc.contributor.author |
Boyd, Peter |
en |
dc.contributor.author |
Brimble, Margaret |
en |
dc.date.accessioned |
2011-09-06T02:21:42Z |
en |
dc.date.issued |
2008 |
en |
dc.identifier.citation |
Acta Crystallogr Sect E Struct Rep Online 64(Pt 8):o1535 2008 |
en |
dc.identifier.issn |
1600-5368 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/7747 |
en |
dc.description.abstract |
In the crystal structure of the racemic title isoxazolidine, C19H27NO, the relative stereochemistry between the phenyl group and the bridgehead H atom is shown to be syn. There are two molecules in the asymmetric unit, one of which is the 7R*,13R* enantiomer, and one of which is the 7S*,13S* enantiomer. These enantiomers adopt different orientations of the phenyl ring with respect to the isoxazolidine ring, with C-C-C-C torsion angles of 63.6 (4) and 86.8 (4)°, respectively. In both enantiomers, the six-membered ring adopts a chair conformation, while the seven-membered ring adopts a twist-chair conformation. |
en |
dc.language |
EN |
en |
dc.publisher |
International Union of Crystallography |
en |
dc.relation.ispartofseries |
Acta Crystallogr Sect E Struct Rep Online |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/1600-5368/ |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.rights.uri |
http://journals.iucr.org/services/copyrightpolicy.html |
en |
dc.subject |
SPIROLIDE-C |
en |
dc.subject |
OSTENFELDII |
en |
dc.title |
(+/-)-2 '-phenylcyclohexanespiro-4 '-(azepano[1,2-b] isoxazolidine) |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1107/S1600536808021867 |
en |
pubs.issue |
8 |
en |
pubs.begin-page |
o1535 |
en |
pubs.volume |
64 |
en |
dc.rights.holder |
Copyright: International Union of Crystallography |
en |
dc.identifier.pmid |
21203240 |
en |
pubs.end-page |
o1535 |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/OpenAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
79480 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
pubs.org-id |
Science Research |
en |
pubs.org-id |
Maurice Wilkins Centre (2010-2014) |
en |
pubs.record-created-at-source-date |
2010-09-01 |
en |
pubs.dimensions-id |
21203240 |
en |