[1,2-bis(diphenylphosphino)ethane]bis-(N,N-dimethyldithiocarbamato)iron(III) tetrafluoroborate

Boyd, Peter; Rickard, CEF

[1,2-bis(diphenylphosphino)ethane]bis-(N,N-dimethyldithiocarbamato)iron(III) tetrafluoroborate

Boyd, Peter ; Rickard, CEF

Identifier: http://hdl.handle.net/2292/7750

Issue Date: 2006-06

Reference: ACTA CRYSTALLOGR E 62:M1431-M1433 Jun 2006

Rights: Copyright: 2006 International Union of Crystallography

Rights (URI): https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm
Rights (URI): http://journals.iucr.org/services/copyrightpolicy.html

Abstract:

The title compound, [Fe(C3H6NS2)2(C26H24P2)]BF4, contains a six-coordinate iron(III) cationic complex, with two bidentate dimethyldithiocarbamate and one 1,2-bis(diphenylphosphino)ethane ligands, and a disordered tetrafluoroborate anion. The cation possesses a crystallographic twofold rotation axis. The cations assemble in the crystal structure in two-dimensional layers via complementary C-H(phenyl) interactions with channels occupied by tetrafluorborate anions.

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