[1,1′-Diferrocenyl-3,3′-(ethane-1,2-diyldinitrilo)dibutanolato] nickel(II) dichloromethane solvate

Boyd, Peter; Johns, PM; Rickard, CEF

[1,1′-Diferrocenyl-3,3′-(ethane-1,2-diyldinitrilo)dibutanolato] nickel(II) dichloromethane solvate

Boyd, Peter ; Johns, PM ; Rickard, CEF

Identifier: http://hdl.handle.net/2292/7752

Issue Date: 2006

Reference: Acta Crystallographica Section E: Structure Reports Online E(62):m3260-m3262 2006

Rights: Copyright: 2006 International Union of Crystallography

Rights (URI): https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm
Rights (URI): http://journals.iucr.org/services/copyrightpolicy.html

Abstract:

The title compound, [Fe2Ni(C5H5)2(C20H20N2O2)]·CH2Cl2, is a four-coordinate square-planar nickel(II) complex with a tetradentate 1,1'-diferrocenyl-3,3'-(ethane-1,2-diyldinitrilo)dibutanolate ligand, which crystallizes with a molecule of dichloromethane. The ferrocene substituents are arranged in a syn conformation with respect to the Ni coordination plane. The complexes stack in an alternating assembly with channels occupied by the solvent molecules.

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