Atom transfer reactions of (TTP)Ti(eta(2)-3-hexyne): Synthesis and molecular structure of trans-(TTP)Ti[OP(Oct)(3)](2)

Atom transfer reactions of (TTP)Ti(eta(2)-3-hexyne): Synthesis and molecular structure of trans-(TTP)Ti[OP(Oct)(3)](2)

Thorman, JL ; Young, VG ; Boyd, Peter ; Guzei, IA ; Woo, LK
Identifier: http://hdl.handle.net/2292/7866
Issue Date: 2001
Reference: INORG CHEM 40(3):499-506 29 Jan 2001
Rights: Copyright: 2001 American Chemical Society
Rights (URI): https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm

Abstract:

Atom and group transfer reactions were found to occur between heterocumulenes and (TTP)Ti(eta (2)-3-hexyne), 1 (TTP = meso-5,10,15,20-tetra-p-(olylporphyrina dianion). The imido derivatives (TTP)Ti=NR (R = Pr-i, 2; Bu-i, 3) were produced upon treatme

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DOI: 10.1021/ic0003426
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