dc.contributor.author |
Mueller, LJ |
en |
dc.contributor.author |
Elliott, DW |
en |
dc.contributor.author |
Kim, KC |
en |
dc.contributor.author |
Reed, CA |
en |
dc.contributor.author |
Boyd, Peter |
en |
dc.date.accessioned |
2011-09-12T04:03:16Z |
en |
dc.date.issued |
2002 |
en |
dc.identifier.citation |
J AM CHEM SOC 124(32):9360-9361 14 Aug 2002 |
en |
dc.identifier.issn |
0002-7863 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/7885 |
en |
dc.description.abstract |
We present a novel nuclear magnetic resonance experiment for establishing through-bond connectivity in solids using scalar coupling-driven correlation. This method, a variant of the popular double-quantum-filtered correlation spectroscopy experiment in liquids, is robust under fast magic-angle-spinning conditions and in the presence of dynamics. In HC60+, where anisotropic molecular motion renders through-space dipolar-driven correlation ineffective, this through-bond correlation method answers a significant structural question by accurately identifying the direct bond between the protonated sp3 hybridized carbon site and the sp2 hybridized cationic site. |
en |
dc.language |
EN |
en |
dc.relation.ispartofseries |
Journal of the American Chemical Society |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0002-7863/ |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.subject |
NUCLEAR-MAGNETIC-RESONANCE |
en |
dc.subject |
ANGLE-SPINNING NMR |
en |
dc.subject |
MAGIC-ANGLE |
en |
dc.subject |
ROTATING SOLIDS |
en |
dc.subject |
CORRELATION SPECTROSCOPY |
en |
dc.subject |
DISTANCE MEASUREMENTS |
en |
dc.subject |
PULSE SEQUENCE |
en |
dc.subject |
C-13-C-13 |
en |
dc.subject |
C-13 |
en |
dc.title |
Establishing through-bond connectivity in solids with NMR: Structure and dynamics in HC60+ |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1021/ja0266619 |
en |
pubs.issue |
32 |
en |
pubs.begin-page |
9360 |
en |
pubs.volume |
124 |
en |
dc.rights.holder |
Copyright: 2002 American Chemical Society |
en |
dc.identifier.pmid |
12167016 |
en |
pubs.end-page |
9361 |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
5017 |
en |
pubs.record-created-at-source-date |
2010-09-01 |
en |
pubs.dimensions-id |
12167016 |
en |