dc.contributor.author |
KITAJIMA, N |
en |
dc.contributor.author |
OSAWA, M |
en |
dc.contributor.author |
IMAI, S |
en |
dc.contributor.author |
FUJISAWA, K |
en |
dc.contributor.author |
MOROOKA, Y |
en |
dc.contributor.author |
HEERWEGH, K |
en |
dc.contributor.author |
REED, CA |
en |
dc.contributor.author |
Boyd, Peter |
en |
dc.date.accessioned |
2011-09-12T04:05:17Z |
en |
dc.date.issued |
1994-10-12 |
en |
dc.identifier.citation |
INORG CHEM 33(21):4613-4614 12 Oct 1994 |
en |
dc.identifier.issn |
0020-1669 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/7904 |
en |
dc.description.abstract |
A mixed valence trinuclear manganese(II,III,II) complex [Mn3(admtrz)6(OH)2(DMF)2(H2O)2]2(ClO4)10·2(admtrz)·3H2O (1), (admtrz=4-amino-3,5-dimethyl-1,2,4-triazole) with hydroxo and 1,2,4-triazole as bridging ligands has been isolated, and characterized by X-ray crystallography and magnetic susceptibility measurements. In each cation structure, the central Mn(III) ion lies on an inversion center and is bridged to each of the external Mn(II) ions by one OH− anion and two admtrz ligands. Each external Mn(II) ion completes its octahedral surroundings with one admtrz, one DMF and one H2O molecule. Complex 1 exhibits weak antiferromagnetic coupling. Analysis of variable temperature magnetic susceptibility data (4–300 K) according to a Heisenberg model yields a J value of −4.47 cm−1. |
en |
dc.language |
English |
en |
dc.publisher |
AMER CHEMICAL SOC |
en |
dc.relation.ispartofseries |
INORGANIC CHEMISTRY |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0020-1669/ |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.subject |
Science & Technology |
en |
dc.subject |
Physical Sciences |
en |
dc.subject |
Chemistry, Inorganic & Nuclear |
en |
dc.subject |
Chemistry |
en |
dc.subject |
BINUCLEAR MANGANESE(III) COMPLEX |
en |
dc.subject |
CRYSTAL-STRUCTURE |
en |
dc.subject |
BIOLOGICAL RELEVANCE |
en |
dc.subject |
MOLECULAR-STRUCTURES |
en |
dc.subject |
MODEL COMPLEXES |
en |
dc.subject |
METAL-COMPLEXES |
en |
dc.subject |
TRINUCLEAR |
en |
dc.subject |
OXIDATION |
en |
dc.subject |
CHEMISTRY |
en |
dc.subject |
CATALASE |
en |
dc.title |
SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A LINEAR TRIMANGANESE(III,II,III) COMPLEX BRIDGED WITH A (MU-HYDROXO)BIS(MU-ACETATO) UNIT |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1021/ic00099a004 |
en |
pubs.issue |
21 |
en |
pubs.begin-page |
4613 |
en |
pubs.volume |
33 |
en |
pubs.author-url |
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=A1994PM68500004&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=6e41486220adb198d0efde5a3b153e7d |
en |
pubs.end-page |
4614 |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
123229 |
en |
pubs.record-created-at-source-date |
2013-06-05 |
en |