Crystal, molecular, and electronic structure of [Ta2Cl 4(μ-Cl)4(PMe3)4]: A metal-metal single bond between eight-co-ordinate tantalum atoms

Boyd, Peter; Jones, TC; Nielson, AJ; Rickard, CEF

dc.contributor.author	Boyd, Peter	en
dc.contributor.author	Jones, TC	en
dc.contributor.author	Nielson, AJ	en
dc.contributor.author	Rickard, CEF	en
dc.date.accessioned	2011-09-14T22:09:21Z	en
dc.date.issued	1984	en
dc.identifier.citation	J CHEM SOC CHEM COMM 1086-1088 1984	en
dc.identifier.issn	0022-4936	en
dc.identifier.uri	http://hdl.handle.net/2292/7948	en
dc.description.abstract	The crystal structure of the title complex shows an MCl4M bridge across a weak Ta–Ta interaction and eight-fold co-ordination about each metal centre; an electronic structure calculation supports the existence of a σ metal–metal bond.	en
dc.language	EN	en
dc.relation.ispartofseries	Journal of the Chemical Society, Chemical Communications	en
dc.rights	Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0022-4936/	en
dc.rights.uri	https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm	en
dc.title	Crystal, molecular, and electronic structure of [Ta2Cl 4(μ-Cl)4(PMe3)4]: A metal-metal single bond between eight-co-ordinate tantalum atoms	en
dc.type	Journal Article	en
dc.identifier.doi	10.1039/C39840001086	en
pubs.issue	16	en
pubs.begin-page	1086	en
dc.rights.holder	Copyright: Royal Society of Chemistry	en
pubs.end-page	1088	en
pubs.publication-status	Published	en
dc.rights.accessrights	http://purl.org/eprint/accessRights/OpenAccess	en
pubs.subtype	Article	en
pubs.elements-id	141894	en
pubs.record-created-at-source-date	2010-09-29	en