A Facile Cross Metathesis-Radical Cyclisation Approach to Monobenzannulated Spiroketals

Liu, Yen-Cheng; Sperry, Jonathan; Jun, D; Brimble, Margaret

dc.contributor.author	Liu, Yen-Cheng	en
dc.contributor.author	Sperry, Jonathan	en
dc.contributor.author	Jun, D	en
dc.contributor.author	Brimble, Margaret	en
dc.date.accessioned	2011-09-18T22:37:05Z	en
dc.date.issued	2009	en
dc.identifier.citation	Synlett 2009(5):793-797 2009	en
dc.identifier.issn	0936-5214	en
dc.identifier.uri	http://hdl.handle.net/2292/8006	en
dc.description.abstract	The synthesis of a series of 5,5-, 5,6-, and 6,6-monobenzannulated spiroketals using a novel cross-metathesis-radical-cyclisation approach is reported. Cross metathesis between two olefin coupling partners resulted in the formation of a heterodimer which upon hydrogenation furnished a saturated alcohol product. Oxidative radical cyclisation then afforded the desired monobenzannulated spiroketals in good overall yield.	en
dc.language	EN	en
dc.publisher	Georg Thieme Verlag Stuttgart New York	en
dc.relation.ispartofseries	Synlett	en
dc.rights	Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0936-5214/	en
dc.rights.uri	https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm	en
dc.subject	cross metathesis	en
dc.subject	radical cyclisation	en
dc.subject	spiroketal	en
dc.subject	rubromycins	en
dc.subject	berkelic acid	en
dc.subject	AROMATIC SPIROACETALS	en
dc.subject	GAMMA-RUBROMYCIN	en
dc.subject	BERKELIC ACID	en
dc.subject	SKELETON	en
dc.subject	STRATEGY	en
dc.subject	CYCLOADDITION	en
dc.subject	MOIETY	en
dc.subject	ETHERS	en
dc.title	A Facile Cross Metathesis-Radical Cyclisation Approach to Monobenzannulated Spiroketals	en
dc.type	Journal Article	en
dc.identifier.doi	10.1055/s-0028-1087942	en
pubs.issue	5	en
pubs.begin-page	793	en
pubs.volume	2009	en
dc.rights.holder	Copyright: Georg Thieme Verlag KG Stuttgart New York.	en
pubs.end-page	797	en
dc.rights.accessrights	http://purl.org/eprint/accessRights/RestrictedAccess	en
pubs.subtype	Article	en
pubs.elements-id	143906	en
pubs.org-id	Science	en
pubs.org-id	Chemistry	en
pubs.org-id	Science Research	en
pubs.org-id	Maurice Wilkins Centre (2010-2014)	en
pubs.record-created-at-source-date	2010-09-01	en