Addition of cyclopentadiene and 2-trimethylsilyloxyfuran to quinones bearing a menthyl ester chiral auxiliary

Addition of cyclopentadiene and 2-trimethylsilyloxyfuran to quinones bearing a menthyl ester chiral auxiliary

Brimble, Margaret ; Duncalf, Letecia ; Reid, DCW ; Roberts, TRR
Identifier: http://hdl.handle.net/2292/8023
Issue Date: 1998
Reference: TETRAHEDRON 54(20):5363-5374 14 May 1998
Rights: Copyright: 1998 Elsevier Ltd.
Rights (URI): https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm

Abstract:

Addition of cyclopentadiene to 2-carbomethoxy-1,4-benzoquinone 9 afforded Diels-Alder adduct 10 using the Lewis acids ZnCl2 and ZnBr2 whereas the fragmenatation product 11 was the major product when using SnCl4 and TiCl4. Addition of cyclopentadiene

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DOI: 10.1016/S0040-4020(98)00211-7
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