An Approach to an Enantioselective Synthesis of Crisamicin A via a Novel Double Hauser-Kraus Annulation Strategy

An Approach to an Enantioselective Synthesis of Crisamicin A via a Novel Double Hauser-Kraus Annulation Strategy

Audrey, O ; Sperry, Jonathan ; Larsen, US ; Brimble, Margaret
Identifier: http://hdl.handle.net/2292/8050
Issue Date: 2008
Reference: TETRAHEDRON 64(18):3912-3927 28 Apr 2008
Rights: Copyright: 2008 Elsevier Ltd.
Rights (URI): https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm

Abstract:

A double Hauser–Kraus annulation between biscyanophthalide 4 and the d-mannose derived enone 39 provides access to an advanced intermediate 54 that is an excellent scaffold to effect an enantioselective total synthesis of crisamicin A 1.

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DOI: 10.1016/j.tet.2008.02.065
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