An Enantioselective Formal Synthesis of Berkelic Acid.

Show simple item record McLeod, MC en Wilson, ZE en Brimble, MA en 2011-09-19T01:33:49Z en 2011-09-19T01:33:49Z en 2011 en
dc.identifier.citation Org Lett 14 Sep 2011 en
dc.identifier.issn 1523-7060 en
dc.identifier.uri en
dc.description.abstract An enantioselective formal synthesis of berkelic acid is described. The key step involves a late-stage silyl enol ether addition to a benzannulated oxonium ion with subsequent spiroketalization leading to construction of the tetracyclic core. Thermodynamically controlled equilibration under acidic conditions affords the desired spiroketal configuration as a single diastereoisomer. en
dc.language ENG en
dc.relation.ispartof Organic Letters en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from en
dc.rights.uri en
dc.source.uri en
dc.title An Enantioselective Formal Synthesis of Berkelic Acid. en
dc.type Journal Article en
dc.identifier.doi 10.1021/ol202265g en
dc.rights.holder Copyright: 2011 American Chemical Society en
dc.rights.accessrights en
pubs.subtype Article en
pubs.elements-id 225025 en Faculty of Science en Chemistry en

Files in this item

Find Full text

This item appears in the following Collection(s)

Show simple item record


Search ResearchSpace