Diastereoselective addition of 2-trimethylsilyloxyfuran to (S)-(+)-2-(p-tolylsulfinyl)-1,4-benzoquinone

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dc.contributor.author Brimble, Margaret en
dc.contributor.author Duncalf, LJ en
dc.contributor.author Reid, DCW en
dc.date.accessioned 2011-09-19T01:45:27Z en
dc.date.issued 1995 en
dc.identifier.citation TETRAHEDRON-ASYMMETR 6(1):263-269 Jan 1995 en
dc.identifier.issn 0957-4166 en
dc.identifier.uri http://hdl.handle.net/2292/8066 en
dc.description.abstract The uncatalyzed addition of 2-trimethylsilyloxyfuran to (S)-(+)-2-(p-tolylsulfinyl)-1,4-benzoquinone 1 afforded a 3.4:1 ratio of the diastereomeric adducts 2:3. Acetonitrile was found to be the optimum solvent whilst the use of Lewis acid catalysts afforded lower overall yields. en
dc.language EN en
dc.publisher PERGAMON-ELSEVIER SCIENCE LTD en
dc.relation.ispartofseries Tetrahedron Asymmetry en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0957-4166/ en
dc.rights.uri https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm en
dc.subject DIELS-ALDER REACTIONS en
dc.subject CONJUGATE ADDITION en
dc.subject ACTIVATED QUINONES en
dc.subject REARRANGEMENT en
dc.subject ANTIBIOTICS en
dc.subject ADDUCTS en
dc.subject ROUTE en
dc.title Diastereoselective addition of 2-trimethylsilyloxyfuran to (S)-(+)-2-(p-tolylsulfinyl)-1,4-benzoquinone en
dc.type Journal Article en
dc.identifier.doi 10.1016/0957-4166(94)00383-M en
pubs.issue 1 en
pubs.begin-page 263 en
pubs.volume 6 en
dc.rights.holder Copyright: 1994 Elsevier Ltd. en
pubs.end-page 269 en
dc.rights.accessrights http://purl.org/eprint/accessRights/RestrictedAccess en
pubs.subtype Article en
pubs.elements-id 132885 en
pubs.org-id Science en
pubs.org-id Chemistry en
pubs.org-id Science Research en
pubs.org-id Maurice Wilkins Centre (2010-2014) en
pubs.record-created-at-source-date 2011-10-06 en


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