Deprotonation and alkylation of 2-methyl-4,5,6,7-tetrahydro-3H-azepine

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Show simple item record Brimble, Margaret en Gorsuch, Stephen en 2011-09-19T01:55:45Z en 1999 en
dc.identifier.citation Australian Journal of Chemistry 52 (10), 965-969, 1999 en
dc.identifier.issn 0004-9425 en
dc.identifier.uri en
dc.description.abstract The deprotonation of 2-methyl-4,5,6,7-tetrahydro-3H-azepine (5) using lithium diisopropylamide was effected at −30°C in tetrahydrofuran. Addition of deuterium oxide resulted in >95% incorporation of deuterium at the exocyclic position. Addition of a range of electrophiles to the organolithium species afforded moderate yields of the alkylation products wherein substitution at the exocyclic position had occurred. en
dc.language EN en
dc.relation.ispartofseries Australian Journal of Chemistry en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from en
dc.rights.uri en
dc.subject SHELLFISH en
dc.subject REAGENTS en
dc.title Deprotonation and alkylation of 2-methyl-4,5,6,7-tetrahydro-3H-azepine en
dc.type Journal Article en
dc.identifier.doi 10.1071/CH99094 en
pubs.issue 10 en
pubs.begin-page 965 en
pubs.volume 52 en
dc.rights.holder Copyright: 1999 CSIRO en
pubs.end-page 969 en
dc.rights.accessrights en
pubs.subtype Article en
pubs.elements-id 2022 en Science en Chemistry en Science Research en Maurice Wilkins Centre (2010-2014) en
pubs.record-created-at-source-date 2010-09-01 en

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