Deprotonation and alkylation of 2-methyl-4,5,6,7-tetrahydro-3H-azepine

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dc.contributor.author Brimble, Margaret en
dc.contributor.author Gorsuch, Stephen en
dc.date.accessioned 2011-09-19T01:55:45Z en
dc.date.issued 1999 en
dc.identifier.citation Australian Journal of Chemistry 52 (10), 965-969, 1999 en
dc.identifier.issn 0004-9425 en
dc.identifier.uri http://hdl.handle.net/2292/8084 en
dc.description.abstract The deprotonation of 2-methyl-4,5,6,7-tetrahydro-3H-azepine (5) using lithium diisopropylamide was effected at −30°C in tetrahydrofuran. Addition of deuterium oxide resulted in >95% incorporation of deuterium at the exocyclic position. Addition of a range of electrophiles to the organolithium species afforded moderate yields of the alkylation products wherein substitution at the exocyclic position had occurred. en
dc.language EN en
dc.relation.ispartofseries Australian Journal of Chemistry en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0004-9425/ en
dc.rights.uri https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm en
dc.subject ALKALOID SYNTHESIS en
dc.subject SHELLFISH en
dc.subject REAGENTS en
dc.title Deprotonation and alkylation of 2-methyl-4,5,6,7-tetrahydro-3H-azepine en
dc.type Journal Article en
dc.identifier.doi 10.1071/CH99094 en
pubs.issue 10 en
pubs.begin-page 965 en
pubs.volume 52 en
dc.rights.holder Copyright: 1999 CSIRO en
pubs.end-page 969 en
dc.rights.accessrights http://purl.org/eprint/accessRights/RestrictedAccess en
pubs.subtype Article en
pubs.elements-id 2022 en
pubs.org-id Science en
pubs.org-id Chemistry en
pubs.org-id Science Research en
pubs.org-id Maurice Wilkins Centre (2010-2014) en
pubs.record-created-at-source-date 2010-09-01 en


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