dc.contributor.author |
Brimble, Margaret |
en |
dc.contributor.author |
PHYTHIAN, S |
en |
dc.contributor.author |
PRABAHARAN, H |
en |
dc.date.accessioned |
2011-09-19T22:06:37Z |
en |
dc.date.issued |
1995-11-21 |
en |
dc.identifier.citation |
J CHEM SOC PERK T 1 2855-2860 21 Nov 1995 |
en |
dc.identifier.issn |
0300-922X |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/8166 |
en |
dc.description.abstract |
The first syntheses of the pyranonaphthoquinone antibiotics 5-epi-arizonin B1 16, 5-epi-arizonin C1 15 and arizonin C1 3 are described. The key steps involve addition of 2-trimethylsilyloxyfuran 12 to the 2-acetylnaphthoquinone 11 affording the adduct 13 which undergoes oxidative rearrangement to a pyranonaphthoquinone system 14 upon treatment with ceric ammonium nitrate. The regioselective synthesis of naphthoquinone 11via oxidation of ketone 10 is described wherein 10 is prepared via addition of furan to 3,4-dimethoxydehydrobenzene followed by treatment with acid. |
en |
dc.language |
EN |
en |
dc.publisher |
ROYAL SOC CHEMISTRY |
en |
dc.relation.ispartofseries |
J CHEM SOC PERK T 1 |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.subject |
KALAFUNGIN |
en |
dc.title |
SYNTHESIS OF ARIZONIN C1 |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1039/P19950002855 |
en |
pubs.issue |
22 |
en |
pubs.begin-page |
2855 |
en |
dc.rights.holder |
Copyright: 1995 The Royal Society of Chemistry |
en |
pubs.end-page |
2860 |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
141856 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
pubs.org-id |
Science Research |
en |
pubs.org-id |
Maurice Wilkins Centre (2010-2014) |
en |
pubs.record-created-at-source-date |
2011-09-20 |
en |