Synthesis of arylspiroketals related to the papulacandins via generation of phthalide oxycarbenium ions

Synthesis of arylspiroketals related to the papulacandins via generation of phthalide oxycarbenium ions

Brimble, MA ; Caprio, Vittorio ; Johnston, AD ; Sidford, M
Identifier: http://hdl.handle.net/2292/8172
Issue Date: 2001
Reference: SYNTHESIS-STUTTGART 855-862 May 2001
Rights: Copyright: Georg Thieme Verlag Stuttgart New York
Rights (URI): https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm

Abstract:

The nucleophilic addition of allylstannanes to oxycarbenium ions generated from phthalide acetate has been studied. The optimum conditions involve the use of trimethylsilyl trifluoromethanesulfonate in dichloromethane at -78 degreesC. Hydroboration o

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DOI: 10.1055/s-2001-13404
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