Synthesis of Chiral Hydroxylated Farnesene Derivatives

ResearchSpace/Manakin Repository

Show simple item record

dc.contributor.author Brimble, Margaret en
dc.contributor.author Rowan, DD en
dc.contributor.author Spicer, Julie en
dc.date.accessioned 2011-09-19T22:56:17Z en
dc.date.issued 1996 en
dc.identifier.citation Synthesis (1): 116-122 1996 en
dc.identifier.issn 0039-7881 en
dc.identifier.uri http://hdl.handle.net/2292/8177 en
dc.description.abstract Asymmetric dihydroxylation of α-farnesene (4) using the ligand (DHQ)2-PHAL afforded predominantly (S,S)-diol 5 in >95% ee. Use of (DHQD)2-PHAL also afforded (R,R)-diol 5 as the major product in >95% ee, however, lower selectivity for the 6,7-position was observed in this case. The isomeric β-farnesene (9) resulted in a preference for the 10,11-olefin forming predominantly diol 11. en
dc.language EN en
dc.relation.ispartofseries Synthesis en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/0039-7881/ en
dc.rights.uri https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm en
dc.subject farnesene en
dc.subject asymmetric dihydroxylation en
dc.subject polyene en
dc.subject ASYMMETRIC DIHYDROXYLATION en
dc.subject ENANTIOSELECTIVE SYNTHESIS en
dc.subject SQUALENE en
dc.title Synthesis of Chiral Hydroxylated Farnesene Derivatives en
dc.type Journal Article en
dc.identifier.doi 10.1055/s-1996-4169 en
pubs.issue 1 en
pubs.begin-page 116 en
dc.rights.holder Copyright: Georg Thieme Verlag KG Stuttgart New York. en
pubs.end-page 122 en
dc.rights.accessrights http://purl.org/eprint/accessRights/RestrictedAccess en
pubs.subtype Article en
pubs.elements-id 133989 en
pubs.org-id Faculty of Medical & Hlth Sci en
pubs.org-id Medical Sciences en
pubs.org-id ACS Research Centre en
pubs.org-id Faculty of Science en
pubs.org-id Chemistry en
pubs.org-id Science Resrch Insts & Centres en
pubs.org-id Maurice Wilkins Centre (2010-2014) en
pubs.record-created-at-source-date 2010-09-01 en


Full text options

Full text for this item is not available in ResearchSpace.

Find Full text

This item appears in the following Collection(s)

Show simple item record

Share

Search ResearchSpace


Advanced Search

Browse