Synthesis of Chiral Hydroxylated Farnesene Derivatives

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Show simple item record Brimble, Margaret en Rowan, DD en Spicer, Julie en 2011-09-19T22:56:17Z en 1996 en
dc.identifier.citation Synthesis (1): 116-122 1996 en
dc.identifier.issn 0039-7881 en
dc.identifier.uri en
dc.description.abstract Asymmetric dihydroxylation of α-farnesene (4) using the ligand (DHQ)2-PHAL afforded predominantly (S,S)-diol 5 in >95% ee. Use of (DHQD)2-PHAL also afforded (R,R)-diol 5 as the major product in >95% ee, however, lower selectivity for the 6,7-position was observed in this case. The isomeric β-farnesene (9) resulted in a preference for the 10,11-olefin forming predominantly diol 11. en
dc.language EN en
dc.relation.ispartofseries Synthesis en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from en
dc.rights.uri en
dc.subject farnesene en
dc.subject asymmetric dihydroxylation en
dc.subject polyene en
dc.subject SQUALENE en
dc.title Synthesis of Chiral Hydroxylated Farnesene Derivatives en
dc.type Journal Article en
dc.identifier.doi 10.1055/s-1996-4169 en
pubs.issue 1 en
pubs.begin-page 116 en
dc.rights.holder Copyright: Georg Thieme Verlag KG Stuttgart New York. en
pubs.end-page 122 en
dc.rights.accessrights en
pubs.subtype Article en
pubs.elements-id 133989 en Medical and Health Sciences en Medical Sciences en Auckland Cancer Research en Science en Chemistry en Science Research en Maurice Wilkins Centre (2010-2014) en
pubs.record-created-at-source-date 2010-09-01 en

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