Synthesis of Thiacrown and Azacrown Ethers Based on a Spiroacetal Framework

Show simple item record Brimble, Margaret en Nikac, Marica en Crumbie, RL en 2011-09-21T22:52:35Z en 2007 en
dc.identifier.citation TETRAHEDRON 63(24):5220-5226 11 Jun 2007 en
dc.identifier.issn 0040-4020 en
dc.identifier.uri en
dc.description.abstract A novel class of thiacrown and azacrown ethers incorporating the 1,7-dioxaspiro[5.5]undecane spiroacetal ring system was prepared by reaction of ditosylate 5 with the appropriate dithiols 9a–c or protected diamine 12a. Spiroacetal ditosylate 5 in turn, was prepared from diol 3 via ozonolysis of bisallyl ether 7 followed by tosylation of the derived diol 8. en
dc.language EN en
dc.publisher Elsevier Ltd. en
dc.relation.ispartofseries Tetrahedron en
dc.rights Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from en
dc.rights.uri en
dc.subject SECONDARY-AMINES en
dc.subject CROWN en
dc.subject MACROCYCLES en
dc.subject POLYETHERS en
dc.subject CHEMISTRY en
dc.subject DESIGN en
dc.subject MOIETY en
dc.subject FAMILY en
dc.title Synthesis of Thiacrown and Azacrown Ethers Based on a Spiroacetal Framework en
dc.type Journal Article en
dc.identifier.doi 10.1016/j.tet.2007.03.174 en
pubs.issue 24 en
pubs.begin-page 5220 en
pubs.volume 63 en
dc.rights.holder Copyright: 2007 Elsevier Ltd. en
pubs.end-page 5226 en
dc.rights.accessrights en
pubs.subtype Article en
pubs.elements-id 74196 en Science en Chemistry en Science Research en Maurice Wilkins Centre (2010-2014) en
pubs.record-created-at-source-date 2010-09-01 en

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