dc.contributor.author |
Brimble, Margaret |
en |
dc.contributor.author |
Sperry, Jonathan |
en |
dc.contributor.editor |
Paquette, LA |
en |
dc.contributor.editor |
Crich, D |
en |
dc.contributor.editor |
Fuchs, PL |
en |
dc.contributor.editor |
Wipf, P |
en |
dc.date.accessioned |
2011-11-06T22:05:58Z |
en |
dc.date.issued |
2008 |
en |
dc.identifier.citation |
In e-EROS Encyclopedia of Reagents for Organic Synthesis. Editors: Paquette LA, Crich D, Fuchs PL, Wipf P. 1-2. John Wiley and Sons Ltd 2008 |
en |
dc.identifier.isbn |
0471936235 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/8705 |
en |
dc.description.abstract |
InChI = 1S/C7H12O2Si/c1-10(2,3)9-7-5-4-6-8-7/h4-6H,1-3H3 InChIKey = ILBCDLOQMRDXLN-UHFFFAOYSA-N (provides 5-substituted 2(5H)-furanones by alkylation,2 aldolization,3 and conjugate addition;4 transforms quinones into furo[3,2-b]benzofurans;5 useful for the four-carbon elongation of sugars6) Alternate Name: TMSOF. Physical Data: bp 44–46 °C/17 mmHg; d 0.93 g mL–1. Solubility: sol most organic solvents, e.g. CH2Cl2, Et2O, benzene, THF, MeCN. Form Supplied in: colorless liquid; commercially available (98% pure) but expensive. Preparative Method: accessible by silylation of 2(5H)-furanone,1c,5b which is obtained at very low cost by oxidation of furfural (see also ). Handling, Storage, and Precautions: flammable liquid; sensitive to moisture. To avoid hydrolysis, it should be kept under Ar at –18 °C or below. For best results, reactions should be performed under strictly anhydrous conditions in aprotic solvents. Use in a fume hood. |
en |
dc.description.uri |
http://librarysearch.auckland.ac.nz/primo_library/libweb/action/display.do?fn=search&doc=uoa_voyager570304&vid=UOA2_A |
en |
dc.publisher |
John Wiley and Sons Ltd |
en |
dc.relation.ispartof |
e-EROS Encyclopedia of Reagents for Organic Synthesis |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.title |
2-Trimethylsilyloxyfuran, CAS No: 61550-02- Update |
en |
dc.type |
Book Item |
en |
dc.identifier.doi |
10.1002/047084289X.rt327.pub2 |
en |
pubs.begin-page |
1 |
en |
dc.rights.holder |
Copyright: John Wiley and Sons Ltd |
en |
pubs.author-url |
http://onlinelibrary.wiley.com/o/eros/articles/rt327/frame.html |
en |
pubs.end-page |
2 |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.elements-id |
81090 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
pubs.org-id |
Science Research |
en |
pubs.org-id |
Maurice Wilkins Centre (2010-2014) |
en |
pubs.record-created-at-source-date |
2010-09-01 |
en |