dc.contributor.author |
Lemon, CM |
en |
dc.contributor.author |
Brothers, Penelope |
en |
dc.contributor.author |
Boitrel, B |
en |
dc.date.accessioned |
2011-11-17T04:53:25Z |
en |
dc.date.issued |
2011 |
en |
dc.identifier.citation |
Dalton Transactions 40(25):6591-6609 2011 |
en |
dc.identifier.issn |
1477-9226 |
en |
dc.identifier.uri |
http://hdl.handle.net/2292/9148 |
en |
dc.description.abstract |
Metalloporphyrin complexes of the period six metals gold, mercury, thallium, lead and bismuth are often overlooked in favour of their lighter congeners. These complexes exhibit unusual coordination geometries, prominently featuring the metal centre residing out the porphyrin plane. Not only are these compounds chemically interesting, but several applications for these complexes are beginning to emerge. Gold and bismuth porphyrins have medicinal applications including novel chemotherapeutics and sensitizers for α-radiotherapy, while gold porphyrins have applications in materials chemistry and catalysis. This perspective serves to highlight trends in the synthesis and structure of these heavy metal complexes as well as illustrate the considerations necessary for rationally designing elaborate porphyrin architectures. |
en |
dc.language |
EN |
en |
dc.publisher |
Royal Society of Chemistry |
en |
dc.relation.ispartofseries |
Journal- Chemical Society Dalton Transactions |
en |
dc.rights |
Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated. Previously published items are made available in accordance with the copyright policy of the publisher. Details obtained from http://www.sherpa.ac.uk/romeo/issn/1477-9226/ |
en |
dc.rights.uri |
https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm |
en |
dc.subject |
RAY CRYSTAL-STRUCTURE |
en |
dc.subject |
PHOTOINDUCED CHARGE SEPARATION |
en |
dc.subject |
GOLD PORPHYRIN |
en |
dc.subject |
MOLECULAR-STRUCTURE |
en |
dc.subject |
ELECTRON-TRANSFER |
en |
dc.subject |
GOLD(III) PORPHYRINS |
en |
dc.subject |
BISMUTH COMPLEXES |
en |
dc.subject |
ZINC PORPHYRIN |
en |
dc.subject |
MESO-TETRAPHENYLPORPHYRIN |
en |
dc.subject |
MERCURY(II) COMPLEXES |
en |
dc.title |
Porphyrin complexes of the period 6 main group and late transition metals |
en |
dc.type |
Journal Article |
en |
dc.identifier.doi |
10.1039/c0dt01711f |
en |
pubs.issue |
25 |
en |
pubs.begin-page |
6591 |
en |
pubs.volume |
40 |
en |
dc.rights.holder |
Copyright: The Royal Society of Chemistry |
en |
dc.identifier.pmid |
21384031 |
en |
pubs.author-url |
http://pubs.rsc.org/en/Content/ArticleLanding/2011/DT/c0dt01711f#!divAbstract |
en |
pubs.end-page |
6609 |
en |
dc.rights.accessrights |
http://purl.org/eprint/accessRights/RestrictedAccess |
en |
pubs.subtype |
Article |
en |
pubs.elements-id |
210694 |
en |
pubs.org-id |
Science |
en |
pubs.org-id |
Chemistry |
en |
dc.identifier.eissn |
1364-5447 |
en |
pubs.record-created-at-source-date |
2011-11-17 |
en |
pubs.dimensions-id |
21384031 |
en |